Room temperature phosphorescence of organic compounds. The effects of moisture, oxygen, and the nature of the support-phosphor interaction

1977 ◽  
Vol 81 (20) ◽  
pp. 1932-1939 ◽  
Author(s):  
E. M. Schulman ◽  
R. T. Parker
Keyword(s):  
Organic Compounds ◽  
Room Temperature ◽  
Room Temperature Phosphorescence

scholarly journals The development of mechanoluminescence from organic compounds: breakthrough and deep insight

2020 ◽  
Vol 4 (2) ◽  
pp. 317-331 ◽  
Author(s):  
Yujun Xie ◽  
Zhen Li
Keyword(s):  
Organic Compounds ◽  
Room Temperature ◽  
Crack Surface ◽  
Deep Insight ◽  
Room Temperature Phosphorescence

The organic mechanoluminescence (ML) happens at the crack surface under force, and the ML composition is becoming more complicated, extending from the normal fluorescence to phosphorescence, persistent room temperature phosphorescence and the photo-sensitive ML.

Invoking ultralong room temperature phosphorescence of purely organic compounds through H-aggregation engineering

2019 ◽  
Vol 6 (6) ◽  
pp. 1259-1264 ◽  
Author(s):  
Jie Yuan ◽  
Shuang Wang ◽  
Yu Ji ◽  
Runfeng Chen ◽  
Qi Zhu ◽  
...  
Keyword(s):  
Phase Transformation ◽  
Organic Compounds ◽  
Room Temperature ◽  
Reversed Phase ◽  
Room Temperature Phosphorescence ◽  
Dark State ◽  
Thermally Activated ◽  
Splitting Energy ◽  
Allowed State

Splitting energy (Δε)-controlled thermally activated reversed phase transformation from the low-lying dark state to the high-lying transition-allowed state of H-aggregation plays a key role in the organic ultralong room-temperature phosphorescence.

Hydrogen bonding boosted the persistent room temperature phosphorescence of pure organic compounds for multiple applications

2019 ◽  
Vol 7 (29) ◽  
pp. 9095-9101 ◽  
Author(s):  
Tingting Zhang ◽  
Heqi Gao ◽  
Anqi Lv ◽  
Ziyi Wang ◽  
Yongyang Gong ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Organic Compounds ◽  
Room Temperature ◽  
Room Temperature Phosphorescence

Pure organic compounds with p-RTP efficiency being enhanced through hydrogen bonding could be fabricated into nanoparticles forin vivoimaging.

Heavy-atom induced room-temperature phosphorescence: a straightforward methodology for the determination of organic compounds in solution

2000 ◽  
Vol 417 (1) ◽  
pp. 19-30 ◽  
Author(s):  
A. Segura-Carretero ◽  
C. Cruces-Blanco ◽  
B. Cañabate-Dı́az ◽  
J.F. Fernández-Sánchez ◽  
A. Fernández-Gutiérrez
Keyword(s):  
Organic Compounds ◽  
Room Temperature ◽  
Heavy Atom ◽  
Room Temperature Phosphorescence

Solid-Matrix Luminescence from Trace Organic Compounds in Glasses Prepared from Sugars

1996 ◽  
Vol 50 (1) ◽  
pp. 53-58 ◽  
Author(s):  
Jiangshan Wang ◽  
Robert J. Hurtubise
Keyword(s):  
Organic Compounds ◽  
Room Temperature ◽  
Solid Matrix ◽  
Organic Analysis ◽  
Trace Organic Compounds ◽  
Room Temperature Phosphorescence ◽  
Solid Supports ◽  
Limits Of Detection ◽  
Clear Glass ◽  
Trace Organic

A new kind of solid matrix, glasses from sugars, was developed for trace organic analysis. Clear glasses of glucose and trehalose were prepared by evaporating the sugar solutions onto solid supports. It was determined that the ratio of methanol to water was very important in forming a clear glass. Also, glasses made from pure trehalose often cracked. However, with the addition of 8–10% NaCl to the trehalose, no cracks were formed. Clear and rigid glasses of both glucose and trehalose/NaCl were obtained on quartz plates. Strong room-temperature fluorescence (RTF) and room-temperature phosphorescence (RTP) were obtained from benzo[ f]quinoline (B[ f]Q), 4-phenylphenol (4-PP), (tetrol I-1), triphenylene, and phenanthrene. The limits of detection (LODs) of both the RTF and RTP for 4-PP and B[ f]Q in the glasses were in the subnanogram milligram range.

scholarly journals Guidelines for measurement of luminescence spectra and quantum yields of inorganic and organometallic compounds in solution and solid state (IUPAC Technical Report)

2016 ◽  
Vol 88 (7) ◽  
pp. 701-711 ◽  
Author(s):  
Hitoshi Ishida ◽  
Jean-Claude Bünzli ◽  
Andrew Beeby
Keyword(s):  
Solid State ◽  
Organic Compounds ◽  
Room Temperature ◽  
Inorganic Compounds ◽  
Organometallic Compounds ◽  
Quantum Yields ◽  
Luminescence Spectra ◽  
Room Temperature Phosphorescence ◽  
Emission Data ◽  
Technical Report

AbstractGuidelines for measuring the luminescence of inorganic compounds, metal complexes, and organometallic compounds are described. Common textbooks and manuals describing luminescence measurements are usually targeted for organic compounds, and are not always suitable for inorganic and organometallic compounds, which emit room-temperature phosphorescence. The report describes problems that researchers may confront while recording emission data and elaborates clear procedures to avoid these problems and provide adequate standardized protocols.

scholarly journals Controlling ultralong room temperature phosphorescence in organic compounds with sulfur oxidation state

2021 ◽  
Vol 12 (1) ◽  
pp. 188-195
Author(s):  
Zhen Xu ◽  
Clàudia Climent ◽  
Christopher M. Brown ◽  
Duane Hean ◽  
Christopher J. Bardeen ◽  
...  
Keyword(s):  
Organic Compounds ◽  
Oxidation State ◽  
Room Temperature ◽  
Sulfur Oxidation ◽  
Intersystem Crossing ◽  
Room Temperature Phosphorescence ◽  
Lone Pairs ◽  
Orbital Mixing

Sulfur lone pairs in bridged dimers enhance intersystem crossing and phosphorescence through orbital mixing and electrostatic screening.

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