DEHYDRATION KINETICS OF 2-BUTANOL OVER A COPPER—CHROMIUM OXIDE CATALYST

1961 ◽  
Vol 65 (7) ◽  
pp. 1089-1093 ◽  
Author(s):  
A. C. Andrews ◽  
J. S. Cantreli
1958 ◽  
Vol 36 (6) ◽  
pp. 921-925 ◽  
Author(s):  
A. S. Perlin ◽  
E. Von Rudloff ◽  
A. P. Tulloch

Treatment of methyl β-L-arabopyranoside under hydrogenolytic conditions with copper chromium oxide catalyst induces extensive isomerization. Products formed include glycosides of D-ribose, D-xylose, D-lyxose, and L-lyxose which together represent about an 80–90% conversion of starting material. Isolation of these compounds shows that carbons 2, 3, and 4 undergo isomerization, but no evidence has been obtained of anomerization. These findings possibly explain the formation of an optically inactive mixture of cis- and trans-tetrahydropyran-3,4-diol under slightly more drastic reaction conditions.


1985 ◽  
Vol 21 (3) ◽  
pp. 324-329 ◽  
Author(s):  
R. P. Gura ◽  
V. M. Vlasenko ◽  
V. A. Kuznetsov ◽  
V. V. Raksha

1985 ◽  
Vol 59 (2) ◽  
pp. 190-200 ◽  
Author(s):  
F. Hanic ◽  
I. Horváth ◽  
G. Plesch ◽  
Ľ. Gáliková

1960 ◽  
Vol 38 (11) ◽  
pp. 2178-2186 ◽  
Author(s):  
H. R. Goldschmid ◽  
A. S. Perlin

A compound formed during the hydrogenolysis of sucrose in ethanol or dioxane at 180 °C, in the presence of copper chromium oxide catalyst, has been characterized as 2,6-anhydro-β-D-fructofuranose (2,5-anhydro-α-D-fructopyranose), a new type of anhydro-ketose. Ethyl α- and β-D-fructofuranosides are also produced when the hydrogenolysis reaction is carried out in ethanol, and various derivatives of these anomeric ketosides have been prepared.


1964 ◽  
Vol 84 (8) ◽  
pp. 729-732
Author(s):  
Tsugio Okada ◽  
Ryoichi Miyake

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