Kinetics of the thermal decomposition of hexafluoroazomethane and the reaction of trifluoromethyl radicals with methyl ethyl ketone

1969 ◽  
Vol 73 (9) ◽  
pp. 2838-2845 ◽  
Author(s):  
Thomas Howard McGee ◽  
Charles E. Waring
Keyword(s):  
Thermal Decomposition ◽  
Methyl Ethyl Ketone ◽  
Methyl Ethyl ◽  
Kinetics Of

The Kinetics of the Thermal Decomposition of Gaseous Methyl Ethyl Ketone1a

1948 ◽  
Vol 70 (12) ◽  
pp. 4073-4081 ◽  
Author(s):  
Chas. E. Waring ◽  
Walter E. Mutter
Keyword(s):  
Thermal Decomposition ◽  
Methyl Ethyl ◽  
Kinetics Of

Kinetics of dehydration of aqueous 2,3-butanediol to methyl ethyl ketone

1982 ◽  
Vol 21 (3) ◽  
pp. 473-477 ◽  
Author(s):  
Richard R. Emerson ◽  
Michael C. Flickinger ◽  
George T. Tsao
Keyword(s):  
Methyl Ethyl Ketone ◽  
Methyl Ethyl ◽  
Kinetics Of

The Mechanism of the Thermal Decomposition of Methyl Ethyl Ketone

1955 ◽  
Vol 77 (24) ◽  
pp. 6453-6457 ◽  
Author(s):  
Chas. E. Waring ◽  
Marshall Spector
Keyword(s):  
Thermal Decomposition ◽  
Methyl Ethyl Ketone ◽  
Methyl Ethyl

Kinetics and hazards of thermal decomposition of methyl ethyl ketone peroxide by DSC

2005 ◽  
Vol 430 (1-2) ◽  
pp. 67-71 ◽  
Author(s):  
Min-Hao Yuan ◽  
Chi-Min Shu ◽  
Arcady A. Kossoy
Keyword(s):  
Thermal Decomposition ◽  
Methyl Ethyl Ketone ◽  
Methyl Ethyl Ketone Peroxide ◽  
Methyl Ethyl

Hemolytic decomposition of di-sec-butyl peroxide

1970 ◽  
Vol 48 (4) ◽  
pp. 615-627 ◽  
Author(s):  
R. Hiatt ◽  
Sandor Szilagyi
Keyword(s):  
Activation Energy ◽  
Thermal Decomposition ◽  
Hydrogen Production ◽  
Methyl Ethyl Ketone ◽  
Methyl Ethyl ◽  
Kcal Mole ◽  
Alkoxy Radicals ◽  
Solvent Cage ◽  
Butyl Peroxide

Rates and products have been determined for the thermal decomposition of sec-butyl peroxide at 110–150 °C in several solvents.The decomposition was shown to be unimolecular with energies of activation in toluene, benzene, and cyclohexane of 35.5 ± 1.0, 33.2 ± 1.0, 33.8 ± 1.0 kcal/mole respectively. The activation energy of thermal decomposition for the deuterated peroxide was found to be 37.2 + 1.0 kcal/mole in toluene.About 70–80% of the products could be explained by known reactions of free alkoxy radicals, and very little, if any, disproportionation of two sec-butoxy radicals in the solvent cage could be detected.The other 20–30% of the peroxide yielded H2 and methyl ethyl ketone. The yield of H2 was unaffected by the nature or the viscosity of the solvent, but H2 was not formed when s-Bu2O2 was photolyzed in toluene at 35 °C nor when the peroxide was thermally decomposed in the gas phase.α,α′-Dideutero-sec-butyl peroxide was prepared and decomposed in toluene at 110–150 °C. The yield of D2 was about the same as the yield of H2 from s-Bu2O2, but the rate of decomposition (at 135 °C) was only 1/1.55 as fast.Mechanisms for hydrogen production are discussed, but none satisfactorily explains all the evidence.

Kinetics of wax crystallization from methyl ethyl ketone solutions

1977 ◽  
Vol 13 (10) ◽  
pp. 712-714 ◽  
Author(s):  
E. T. Klimenko ◽  
M. N. Seliverstov ◽  
M. I. Fal'kovich
Keyword(s):  
Methyl Ethyl Ketone ◽  
Methyl Ethyl ◽  
Wax Crystallization ◽  
Kinetics Of

Study of thermal decomposition of methyl ethyl ketone peroxide using DSC and simulation

2007 ◽  
Vol 142 (3) ◽  
pp. 765-770 ◽  
Author(s):  
Jo-Ming Tseng ◽  
Ying-Yu Chang ◽  
Teh-Sheng Su ◽  
Chi-Min Shu
Keyword(s):  
Thermal Decomposition ◽  
Methyl Ethyl Ketone ◽  
Methyl Ethyl Ketone Peroxide ◽  
Methyl Ethyl
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