Free radical chain reaction in the radiolysis and photolysis of isobutyl bromide

1970 ◽  
Vol 74 (10) ◽  
pp. 2074-2082 ◽  
Author(s):  
Donna K. Bakale ◽  
Hugh A. Gillis
Keyword(s):  
Free Radical ◽  
Chain Reaction ◽  
Radical Chain ◽  
Free Radical Chain Reaction ◽  
Radical Chain Reaction

The reaction of thionitrites with barton esters: a convenient free radical chain reaction for decarboxylative nitrosation

Tetrahedron ◽  
1999 ◽  
Vol 55 (12) ◽  
pp. 3573-3584 ◽  
Author(s):  
Pierre Girard ◽  
Nadine Guillot ◽  
William B. Motherwell ◽  
Robyn S. Hay-Motherwell ◽  
Pierre Potier
Keyword(s):  
Free Radical ◽  
Chain Reaction ◽  
Radical Chain ◽  
Free Radical Chain Reaction ◽  
Radical Chain Reaction

Rubber, Polyisoprenes, and Allied Compounds. VII. Action of Nitric Oxide

1944 ◽  
Vol 17 (4) ◽  
pp. 772-778
Author(s):  
George F. Bloomfield ◽  
G. A. Jeffrey
Keyword(s):  
Nitric Oxide ◽  
Free Radical ◽  
Reaction Mechanism ◽  
Nitro Compounds ◽  
Chain Reaction ◽  
Considerable Part ◽  
Radical Chain ◽  
Ethylenic Carbon ◽  
Free Radical Chain Reaction ◽  
Radical Chain Reaction

Abstract The reaction of nitric oxide with the olefins cyclohexene, 1-methylcyclohexene, dihydromyrcene, and rubber presents characteristics of a free-radical, chain reaction. In the products, the molecular ratio of combined oxygen to nitrogen is considerably in excess of 1:1, the nitrogen atom being generally directly linked to carbon. In many instances definite nitro compounds have been isolated, and a considerable part of the attack appears to proceed at the ethylenic carbon atoms, either by substitution or addition of NO2 and N2O3 groups. The precise reaction mechanism is obscure.

scholarly journals The discovery of new phloroglucinol glycosides from Agrimonia pilosa and the mechanism of oxidative dearomatization of the methyl-substituted phloroglucinol derivatives

RSC Advances ◽  
2021 ◽  
Vol 11 (36) ◽  
pp. 22273-22277
Author(s):  
Jia Zhang ◽  
Ya-Nan Yang ◽  
Jian-Shuang Jiang ◽  
Zi-Ming Feng ◽  
Xiang Yuan ◽  
...  
Keyword(s):  
Free Radical ◽  
Chain Reaction ◽  
Radical Chain ◽  
Oxidative Dearomatization ◽  
Phloroglucinol Derivatives ◽  
Free Radical Chain Reaction ◽  
Radical Chain Reaction

New phloroglucinol glycosides, aglycones, and oxidative dearomatized products of aglycones were discovered from Agrimonia pilosa, and the mechanism of the auto oxidative dearomatization was disclosed as a free radical chain reaction with 3O2.

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