Raman study of aqueous rare earth nitrate solutions in liquid and glassy states

1984 ◽  
Vol 88 (13) ◽  
pp. 2787-2792 ◽  
Author(s):  
H. Kanno ◽  
J. Hiraishi



1979 ◽  
Vol 24 (4) ◽  
pp. 298-305 ◽  
Author(s):  
Frank H. Spedding ◽  
James L. Baker ◽  
John P. Walters


1975 ◽  
Vol 20 (1) ◽  
pp. 88-93 ◽  
Author(s):  
Frank H. Spedding ◽  
Loren E. Shiers ◽  
Joseph A. Rard


Calphad ◽  
2019 ◽  
Vol 67 ◽  
pp. 101683 ◽  
Author(s):  
Aleksey I. Maksimov ◽  
Nikita A. Kovalenko ◽  
Irina A. Uspenskaya


2013 ◽  
Vol 838-841 ◽  
pp. 2806-2810
Author(s):  
Juch Kuang

Experimental results show that the samples gained in bath added Rare earth nitrate (REN), relative to the sample got in bath without REN, improve the anti-corrosion power of the coating because of increasing of covering rate of formless crystal Zn2Fe(PO4)2·4H2O (marked P) crystals and the ratio of P/(P+H) (H is the mark of Zn3(PO4)2 crystal) in the coating, combination of which with components parsing by EDS indicates that the sequence of contribution elements P and Zn to erosion resistance of coatings is P>Zn. And the correlative mechanism was discussed, which has it clear that RE is materially a catalyst holding excellent ability of carrying oxygen and cathode depolarization, its concentration gets so constant in certain range that it is much steadier and more efficient than the usual consumptive oxidants like nitrates. In a word, REN plays the role of surface regulator, accelerant and densification agent, which speeds up the phosphating, and bids it effective to enhance the anti-corrosion power of the coating. The addition of REN, not only promote the phosphating film formation and substantial reduction or exemption of nitrite. So, REN is green phosphating accelerator of live up to one's name.



2013 ◽  
Vol 33 (15-16) ◽  
pp. 2915-2923 ◽  
Author(s):  
Alfian Noviyanto ◽  
Seung-Woo Han ◽  
Hyun-Woo Yu ◽  
Dang-Hyok Yoon


1970 ◽  
Vol 1 (2) ◽  
pp. 942-942 ◽  
Author(s):  
J. F. Scott


2014 ◽  
Vol 602-603 ◽  
pp. 1017-1020 ◽  
Author(s):  
Qi Zhu ◽  
J.G. Li ◽  
Xiao Dong Li ◽  
Xu Dong Sun

Two dimensional nanophosphors of high quality play an important role in the miniaturization and intelligentization of opto-electronic components. In this present work, ultra-large (30μm) single crystals of (Y0.95Eu0.05)2(OH)5NO3·nH2O layered rare earth hydroxide (LRH) with a hexagonal shape have been synthisized via autoclaving the rare-earth nitrate/NH4OH reaction system in the presence of ammonium nitrate (NH4NO3). The nitrate ions, existing in the interlayer gallery of layered rare earth hydroxide, exhibit facile exchanges with oleate anions by hydrothermal anion exchange. Furthermore, the interlayer distance can thus be expanded from ~0.9 nm for the pristine LRHs to ~3.60 nm for the intercalated ones, which are then efficiently delaminated into unilamellar nanosheets with a lateral size of 10μm and a thickness of ~1.50 nm. The obtained nanosheets are single crystaline. Highly [11 oriented, dense (Y0.95Eu0.05)2O3 phosphor films with excellent optical transparency and a greatly enhanced luminescence intensity have been constructed via self-assembly of ultra-large unilamellar LRH nanosheets, followed by proper annealing.



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