Solvent effects on the thermochemistry of free-radical reactions

1989 ◽  
Vol 111 (9) ◽  
pp. 3311-3314 ◽  
Author(s):  
J. M. Kanabus-Kaminska ◽  
B. C. Gilbert ◽  
D. Griller
Keyword(s):  
Free Radical ◽  
Solvent Effects ◽  
Radical Reactions ◽  
Free Radical Reactions

Solvent Effects on the Oxidative Free Radical Reactions of 2-Amino-1,4-naphthoquinones.

ChemInform ◽  
2005 ◽  
Vol 36 (14) ◽  
Author(s):  
Chao-Ming Tseng ◽  
Yi-Lung Wu ◽  
Che-Ping Chuang
Keyword(s):  
Free Radical ◽  
Solvent Effects ◽  
Radical Reactions ◽  
Free Radical Reactions

Solvent Effects in Free-Radical Reactions.

1967 ◽  
Vol 25 (12) ◽  
pp. 1108-1120 ◽  
Author(s):  
Hideki SAKURAI ◽  
Akira HOSOMI
Keyword(s):  
Free Radical ◽  
Solvent Effects ◽  
Radical Reactions ◽  
Free Radical Reactions

Influence of the solvent on the transmission of polar effects in free radical reactions. A theoretical study

1988 ◽  
Vol 53 (11) ◽  
pp. 2714-2721 ◽  
Author(s):  
Robert Ponec ◽  
Milan Hájek
Keyword(s):  
Free Radical ◽  
Solvent Effects ◽  
Theoretical Study ◽  
Chemical Reactivity ◽  
Theoretical Description ◽  
Radical Reactions ◽  
Combined Approach ◽  
Free Radical Reactions ◽  
General Methodology ◽  
Charge Model

The influence of the solvents on the transmission of polar effects in free radical reactions has been analysed theoretically by using the combined approach based on the incorporation of delocalizabilities as static indices of chemical reactivity into the framework of virtual charge model. The possibility of using this theoretical description as a general methodology of characterizing solvent effects is discussed.

ChemInform Abstract: Solvent Effects on the Thermochemistry of Free-Radical Reactions.

ChemInform ◽  
1989 ◽  
Vol 20 (32) ◽  
Author(s):  
J. M. KANABUS-KAMINSKA ◽  
B. C. GILBERT ◽  
D. GRILLER
Keyword(s):  
Free Radical ◽  
Solvent Effects ◽  
Radical Reactions ◽  
Free Radical Reactions

Solvent effects on the oxidative free radical reactions of 2-amino-1,4-naphthoquinones

Tetrahedron ◽  
2004 ◽  
Vol 60 (52) ◽  
pp. 12249-12260 ◽  
Author(s):  
Chao-Ming Tseng ◽  
Yi-Lung Wu ◽  
Che-Ping Chuang
Keyword(s):  
Free Radical ◽  
Solvent Effects ◽  
Radical Reactions ◽  
Free Radical Reactions

The initial reaction mechanism and thermal sensitivity of a fluoropolymer-containing energetic molecular system: the coupling effect of interfacial interactions and free radical reactions

CrystEngComm ◽  
2021 ◽  
Vol 23 (16) ◽  
pp. 3006-3014
Author(s):  
Wen Qian
Keyword(s):  
Free Radical ◽  
Coupling Effect ◽  
Molecular System ◽  
Thermal Sensitivity ◽  
Radical Reactions ◽  
Initial Reaction ◽  
Interfacial Interactions ◽  
Free Radical Reactions ◽  
Molecular Systems ◽  
Reactive Molecular Dynamics

A strategy combining classic and reactive molecular dynamics is applied to find the coupling effect of interfacial interactions and free radical reactions during the initial thermal decomposition of fluoropolymer-containing molecular systems.

Further studies on free-radical pathology in the major central nervous system disorders: effect of very high doses of methylprednisolone on the functional outcome, morphology, and chemistry of experimental spinal cord impact injury

1982 ◽  
Vol 60 (11) ◽  
pp. 1415-1424 ◽  
Author(s):  
H. B. Demopoulos ◽  
E. S. Flamm ◽  
M. L. Seligman ◽  
D. D. Pietronigro ◽  
J. Tomasula ◽  
...  
Keyword(s):  
Spinal Cord ◽  
Central Nervous System ◽  
Nervous System ◽  
Free Radical ◽  
Tissue Injury ◽  
Functional Restoration ◽  
Radical Reactions ◽  
Free Radical Reactions ◽  
Cord Injury

The hypothesis that pathologic free-radical reactions are initiated and catalyzed in the major central nervous system (CNS) disorders has been further supported by the current acute spinal cord injury work that has demonstrated the appearance of specific, cholesterol free-radical oxidation products. The significance of these products is suggested by the fact that: (i) they increase with time after injury; (ii) their production is curtailed with a steroidal antioxidant; (iii) high antioxidant doses of the steroidal antioxidant which curtail the development of free-radical product prevent tissue degeneration and permit functional restoration. The role of pathologic free-radical reactions is also inferred from the loss of ascorbic acid, a principal CNS antioxidant, and of extractable cholesterol. These losses are also prevented by the steroidal antioxidant. This model system is among others in the CNS which offer distinctive opportunities to study, in vivo, the onset and progression of membrane damaging free-radical reactions within well-defined parameters of time, extent of tissue injury, correlation with changes in membrane enzymes, and correlation with readily measurable in vivo functions.

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