Oxidation of tert-butyl alcohol to isobutylene oxide on a silver(110) surface: the role of unactivated carbon-hydrogen bonds in product selectivity

1989 ◽  
Vol 111 (11) ◽  
pp. 3826-3835 ◽  
Author(s):  
Robert L. Brainard ◽  
Robert J. Madix
Keyword(s):  
Hydrogen Bonds ◽  
Butyl Alcohol ◽  
Product Selectivity ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Carbon Hydrogen Bonds

Thermodynamic and Kinetic Investigation of the Solvent Effect on the Oxidation of [Co(en)2SCH2COO]+ with S2O82- In Water-Methanol and Water-tert-Butyl Alcohol Mixtures

1993 ◽  
Vol 58 (5) ◽  
pp. 1001-1006 ◽  
Author(s):  
Oľga Vollárová ◽  
Ján Benko
Keyword(s):  
Transfer Functions ◽  
Activation Parameters ◽  
Butyl Alcohol ◽  
Oxidation Of Co ◽  
Kinetics Of Oxidation ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Alcohol Mixtures ◽  
Kinetics Of

The kinetics of oxidation of [Co(en)2SCH2COO]+ with S2O82- was studied in water-methanol and water-tert-butyl alcohol mixtures. Changes in the reaction activation parameters ∆H≠ and ∆S≠ with varying concentration of the co-solvent depend on the kind of the latter, which points to a significant role of salvation effects. The solvation effect on the reaction is discussed based on a comparison of the transfer functions ∆Ht0, ∆St0 and ∆Gt0 for the initial and transition states with the changes in the activation parameters accompanying changes in the CO-solvent concentration. The transfer enthalpies of the reactant were obtained from calorimetric measurements.

Interactions between azines and alcohols: a rotational study of pyridine–tert-butyl alcohol

2019 ◽  
Vol 21 (7) ◽  
pp. 3545-3549 ◽  
Author(s):  
Lorenzo Spada ◽  
Iciar Uriarte ◽  
Weixing Li ◽  
Luca Evangelisti ◽  
Emilio J. Cocinero ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Butyl Alcohol ◽  
Hydroxyl Group ◽  
Intermolecular Hydrogen Bonds ◽  
Tert Butyl ◽  
Type Complex ◽  
Tert Butyl Alcohol ◽  
Ubbelohde Effect

The observed spectrum identifies aCssymmetry σ-type complex, with the two subunits held together by coplanar “classical” O–H⋯N and weak C–H⋯π intermolecular hydrogen bonds. The O⋯N distance decreases by 4 mÅ upon deuteration of the hydroxyl group (reverse Ubbelohde effect).

Spectral investigation of the hydrogen bonds of tert-butyl alcohol and phenol with some electron-donor solvents

1972 ◽  
Vol 17 (6) ◽  
pp. 1588-1592 ◽  
Author(s):  
B. V. Rassadin ◽  
A. V. Iogansen ◽  
V. A. Marchenko ◽  
F. S. Yakushin ◽  
A. I. Shatenshtein
Keyword(s):  
Hydrogen Bonds ◽  
Electron Donor ◽  
Butyl Alcohol ◽  
Spectral Investigation ◽  
Tert Butyl ◽  
Tert Butyl Alcohol

scholarly journals On the competition between weak O H⋯F and C H⋯F hydrogen bonds, in cooperation with C H⋯O contacts, in the difluoromethane – tert-butyl alcohol cluster

2017 ◽  
Vol 337 ◽  
pp. 90-95 ◽  
Author(s):  
Lorenzo Spada ◽  
Nicola Tasinato ◽  
Giulio Bosi ◽  
Fanny Vazart ◽  
Vincenzo Barone ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Butyl Alcohol ◽  
Tert Butyl ◽  
Tert Butyl Alcohol

scholarly journals Impacts of Sn(II) doping on the Keggin heteropolyacid-catalyzed etherification of glycerol with tert-butyl alcohol

2021 ◽  
pp. 116913
Author(s):  
Márcio José da Silva ◽  
Diego Morais Chaves ◽  
Sukarno Olavo ferreira ◽  
Rene Chagas da Silva ◽  
Jose Balena Gabriel Filho ◽  
...  
Keyword(s):  
Butyl Alcohol ◽  
Tert Butyl ◽  
Tert Butyl Alcohol

Selective synthesis of 2,5-dimethyl-2,4-hexadiene by condensation of iso-butyl aldehyde with tert-butyl alcohol over molecular sieve catalysts

2004 ◽  
Vol 5 (1) ◽  
pp. 41-43 ◽  
Author(s):  
Hua Wang ◽  
Zhongmin Liu ◽  
Chenglin Sun ◽  
Gongwei Wang
Keyword(s):  
Molecular Sieve ◽  
Butyl Alcohol ◽  
Selective Synthesis ◽  
Tert Butyl ◽  
Tert Butyl Alcohol
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