New carbon-carbon bond-forming reaction of carbon monoxide: remarkable trialkylation of a carbonyl ligand in a molybdenum pentadienyl complex

1985 ◽  
Vol 107 (26) ◽  
pp. 8296-8297 ◽  
Author(s):  
Michael S. Kralik ◽  
John P. Hutchinson ◽  
Richard D. Ernst
Keyword(s):  
Carbon Monoxide ◽  
Carbonyl Ligand ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond

Carbon-carbon bond-forming reactions of cobaltacyclopentene/cobaltaoxanorbornadiene complexes with isocyanides, carbon monoxide, and alkynes

1988 ◽  
Vol 7 (5) ◽  
pp. 1073-1083 ◽  
Author(s):  
Maryrose. Scozzafava ◽  
Alan M. Stolzenberg
Keyword(s):  
Carbon Monoxide ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions

Acetylene Radical-Cations in Carbon-Carbon Bond Forming Reactio ns

2017 ◽  
Vol 14 (3) ◽  
Author(s):  
Aleksander V. Vasilyev
Keyword(s):  
Radical Cations ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond

scholarly journals Front Cover: Reductive Carbon–Carbon Bond Forming Reactions with Carbonyls Mediated by Rh–H Complexes (Eur. J. Org. Chem. 42/2020)

2020 ◽  
Vol 2020 (42) ◽  
pp. 6501-6501
Author(s):  
Kazuyuki Sato ◽  
Motoyuki Isoda ◽  
Atsushi Tarui ◽  
Masaaki Omote
Keyword(s):  
Carbon Bond ◽  
Front Cover ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions

Nickel-Catalyzed Electronically-Reversed Enantioselective Hydrocarbofunctionalizations of Acrylamides

Synlett ◽  
2021 ◽  
Author(s):  
Lou Shi ◽  
Wei Shu
Keyword(s):  
Nickel Catalyst ◽  
Functional Group ◽  
Optically Active ◽  
Forming Process ◽  
Carbon Bond ◽  
Bond Forming ◽  
Synthetic Strategy ◽  
Carbon Carbon Bond ◽  
Wide Range ◽  
Simple Protocol

Asymmetric hydrocarbofunctionalizations of alkenes has emerged as an efficient synthetic strategy for accessing optically active molecules via carbon-carbon bond-forming process from readily available alkenes and carbo-electrophiles. Herein, we present a summary of the efforts from our group to control the regio- and enantioselectivity of hydrocarbofunctionalizations of electron-deficient alkenes with a nickel catalyst and chiral bisoxazolidine ligand. The reaction undergoes electron-reversed hydrocarbofunctionalizations acrylamides with excellent enantioselectivity. This operationally simple protocol enables the asymmetric hydroalkylation, hydrobenzylation and hydropropargylation of acrylamides. This reaction is useful for preparing a wide range of α-branched chiral amides with broad functional group tolerance.

ChemInform Abstract: Nickel-Catalyzed Carbon-Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations.

ChemInform ◽  
2013 ◽  
Vol 44 (26) ◽  
pp. no-no
Author(s):  
Susan L. Zultanski ◽  
Gregory C. Fu
Keyword(s):  
Alkyl Halides ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Tertiary Alkyl

scholarly journals Aromatic Cations from Oxidative Carbon–Hydrogen Bond Cleavage in Bimolecular Carbon–Carbon Bond Forming Reactions

2012 ◽  
Vol 77 (15) ◽  
pp. 6574-6582 ◽  
Author(s):  
Dane J. Clausen ◽  
Paul E. Floreancig
Keyword(s):  
Hydrogen Bond ◽  
Bond Cleavage ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions
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