Intermediates in nucleophilic aromatic substitution. 18. The elusive 1,1-Meisenheimer complex from 2,4,6-trinitroanisole and aryloxide ions. A stopped-flow temperature-jump study

Claude F. Bernasconi; Morris C. Muller

doi:10.1021/ja00485a043

Intermediates in nucleophilic aromatic substitution. 18. The elusive 1,1-Meisenheimer complex from 2,4,6-trinitroanisole and aryloxide ions. A stopped-flow temperature-jump study

Journal of the American Chemical Society ◽

10.1021/ja00485a043 ◽

1978 ◽

Vol 100 (17) ◽

pp. 5530-5533 ◽

Cited By ~ 14

Author(s):

Claude F. Bernasconi ◽

Morris C. Muller

Keyword(s):

Temperature Jump ◽

Nucleophilic Aromatic Substitution ◽

Stopped Flow ◽

Aromatic Substitution ◽

Flow Temperature

Intermediates in nucleophilic aromatic substitution. VII. Stopped-flow temperature-jump study of the transient 1,3-methoxide ion adduct of 2,4,6-trinitroanisole in methanol

Journal of the American Chemical Society ◽

10.1021/ja00754a047 ◽

1971 ◽

Vol 93 (25) ◽

pp. 6975-6977 ◽

Cited By ~ 22

Author(s):

Claude F. Bernasconi

Keyword(s):

Temperature Jump ◽

Nucleophilic Aromatic Substitution ◽

Stopped Flow ◽

Aromatic Substitution ◽

Flow Temperature ◽

Methoxide Ion

ChemInform Abstract: INTERMEDIATES IN NUCLEOPHILIC AROMATIC SUBSTITUTION. 18. THE ELUSIVE 1,1-MEISENHEIMER COMPLEX FROM 2,4,6-TRINITROANISOLE AND ARYLOXIDE IONS. A STOPPED-FLOW TEMPERATURE-JUMP STUDY

Chemischer Informationsdienst ◽

10.1002/chin.197848085 ◽

1978 ◽

Vol 9 (48) ◽

Author(s):

C. F. BERNASCONI ◽

M. C. MULLER

Keyword(s):

Temperature Jump ◽

Nucleophilic Aromatic Substitution ◽

Stopped Flow ◽

Aromatic Substitution ◽

Flow Temperature

ChemInform Abstract: INTERMEDIATES IN NUCLEOPHILIC AROMATIC SUBSTITUTION PART 11, SPIRO MEISENHEIMER COMPLEX OF N,N′-DIMETHYL-N-PICRYLETHYLENEDIAMINE, PARTIALLY RATE-LIMITING PROTON TRANSFER OF COMPLEX FORMATION, A TEMPERATURE-JUMP STUDY

Chemischer Informationsdienst ◽

10.1002/chin.197417108 ◽

1974 ◽

Vol 5 (17) ◽

pp. no-no

Author(s):

CLAUDE F. BERNASCONI ◽

CONSTANTIN L. GEHRIGER

Keyword(s):

Complex Formation ◽

Proton Transfer ◽

Temperature Jump ◽

Nucleophilic Aromatic Substitution ◽

Aromatic Substitution ◽

Rate Limiting

Intermediates in nucleophilic aromatic substitution. VIII. Temperature-jump and equilibrium study of the spiro Meisenheimer complex of N-2-hydroxyethyl-N-methyl-2,4-dinitroaniline

The Journal of Organic Chemistry ◽

10.1021/jo00943a020 ◽

1973 ◽

Vol 38 (3) ◽

pp. 500-507 ◽

Cited By ~ 7

Author(s):

Claude F. Bernasconi ◽

Rita H. DeRossi

Keyword(s):

Temperature Jump ◽

Nucleophilic Aromatic Substitution ◽

Aromatic Substitution ◽

Equilibrium Study

Intermediates in nucleophilic aromatic substitution. I. Temperature jump study of the decomposition of 1,1-dimethoxy- 2,4-dinitrocyclohexadienate in methanol

Journal of the American Chemical Society ◽

10.1021/ja01020a036 ◽

1968 ◽

Vol 90 (18) ◽

pp. 4982-4988 ◽

Cited By ~ 15

Author(s):

Claude F. Bernasconi

Keyword(s):

Temperature Jump ◽

Nucleophilic Aromatic Substitution ◽

Aromatic Substitution

Comparative Study of Temperature-Induced Association of Cyclic and Linear Poly(N-isopropylacrylamide) Chains in Dilute Solutions by Laser Light Scattering and Stopped-Flow Temperature Jump

Macromolecules ◽

10.1021/ma702196g ◽

2008 ◽

Vol 41 (12) ◽

pp. 4416-4422 ◽

Cited By ~ 83

Author(s):

Jing Ye ◽

Jian Xu ◽

Jinming Hu ◽

Xiaofeng Wang ◽

Guangzhao Zhang ◽

...

Keyword(s):

Light Scattering ◽

Comparative Study ◽

Temperature Jump ◽

Laser Light ◽

Laser Light Scattering ◽

Stopped Flow ◽

Dilute Solutions ◽

Flow Temperature ◽

Linear Poly

Intermediates in nucleophilic aromatic substitution. II. Temperature-jump study of the interaction of 1,3,5-trinitrobenzene with aliphatic amines in 10% dioxane-90% water. Concurrent nucleophilic attack on the aromatic carbon and on the nitro group

Journal of the American Chemical Society ◽

10.1021/ja00704a021 ◽

1970 ◽

Vol 92 (1) ◽

pp. 129-137 ◽

Cited By ~ 21

Author(s):

Claude F. Bernasconi

Keyword(s):

Nitro Group ◽

Temperature Jump ◽

Aliphatic Amines ◽

Nucleophilic Aromatic Substitution ◽

Nucleophilic Attack ◽

Aromatic Substitution ◽

Aromatic Carbon

Kinetics of thermo-induced micelle-to-vesicle transitions in a catanionic surfactant system investigated by stopped-flow temperature jump

Physical Chemistry Chemical Physics ◽

10.1039/c0cp02856h ◽

2011 ◽

Vol 13 (27) ◽

pp. 12545 ◽

Cited By ~ 17

Author(s):

Jingyan Zhang ◽

Shiyong Liu

Keyword(s):

Temperature Jump ◽

Stopped Flow ◽

Flow Temperature ◽

Catanionic Surfactant ◽

Surfactant System ◽

Kinetics Of

Versatile Stopped Flow Temperature Jump Apparatus

Review of Scientific Instruments ◽

10.1063/1.1720312 ◽

1966 ◽

Vol 37 (6) ◽

pp. 746-750 ◽

Cited By ~ 43

Author(s):

James E. Erman ◽

Gordon G. Hammes

Keyword(s):

Temperature Jump ◽

Stopped Flow ◽

Flow Temperature

Absolute Light Scattering Calibration of the Stopped-Flow Spectrophotometer with Application to the Kinetics of Formation of Monodispersed Colloidal Hematite

Applied Spectroscopy ◽

10.1366/0003702874449048 ◽

1987 ◽

Vol 41 (3) ◽

pp. 402-407 ◽

Cited By ~ 7

Author(s):

Wan Peter Hsu ◽

Ramesh C. Patel ◽

Egon Matijevic

Keyword(s):

Colloidal Silica ◽

Temperature Jump ◽

Scattered Light ◽

Calibration Method ◽

Stopped Flow ◽

Flow Temperature ◽

Hydrous Oxides ◽

Solid Iron ◽

Kinetics Of Formation ◽

Kinetics Of

A calibration method based on absolute intensities of scattered light from colloidal silica was developed to standardize the stopped-flow temperature jump spectrophotometer (SFTJ). The need for such calibration was exemplified by the study of the temperature effect on the Rayleigh ratio changes during the formation of solid iron (hydrous) oxides.