Carbon orbital hybridization in some organoplatinum compounds

1970 ◽  
Vol 92 (8) ◽  
pp. 2595-2597 ◽  
Author(s):  
Christopher David. Cook ◽  
Kai Yan. Wan
Keyword(s):  
Orbital Hybridization ◽  
Organoplatinum Compounds

Metal-Metal Cooperative Bond Activation by Heterobimetallic Alkyl, Aryl, and Acetylide PtII/CuI Complexes

2020 ◽  
Author(s):  
Shubham Deolka ◽  
Orestes Rivada Wheelaghan ◽  
Sandra Aristizábal ◽  
Robert Fayzullin ◽  
Shrinwantu Pal ◽  
...  
Keyword(s):  
Alkyl Group ◽  
Bond Activation ◽  
Bond Cleavage ◽  
Terminal Alkyne ◽  
Alkyl Aryl ◽  
Metal Metal ◽  
The Stability ◽  
Selective Formation ◽  
Organoplatinum Compounds

We report selective formation of heterobimetallic PtII/CuI complexes that demonstrate how facile bond activation processes can be achieved by altering reactivity of common organoplatinum compounds through their interaction with another metal center. The interaction of the Cu center with Pt center and with a Pt-bound alkyl group increases the stability of PtMe2 towards undesired rollover cyclometalation. The presence of the CuI center also enables facile transmetalation from electron-deficient tetraarylborate [B(ArF)4]- anion and mild C-H bond cleavage of a terminal alkyne, which was not observed in the absence of an electrophilic Cu center. The DFT study indicates that the role of Cu center acts as a binding site for alkyne substrate, while activating its terminal C-H bond.

Organoplatinum compounds VII

1998 ◽  
Vol 559 (1-2) ◽  
pp. 191-196 ◽  
Author(s):  
H Donath ◽  
E.V Avtomonov ◽  
I Sarraje ◽  
K.-H von Dahlen ◽  
M El-Essawi ◽  
...  
Keyword(s):  
Organoplatinum Compounds

scholarly journals Orbital Hybridization and Magnetic Coupling at Cuprate–Manganite Interfaces Driven by Manganite Doping

2020 ◽  
Vol 3 (6) ◽  
pp. 2000016
Author(s):  
Christoph Schlueter ◽  
Nan Yang ◽  
Claudio Mazzoli ◽  
Claudia Cantoni ◽  
Antonello Tebano ◽  
...  
Keyword(s):  
Magnetic Coupling ◽  
Orbital Hybridization

Defining kerogen maturity from orbital hybridization by machine learning

Fuel ◽  
2022 ◽  
Vol 310 ◽  
pp. 122250
Author(s):  
Jun Ma ◽  
Dongliang Kang ◽  
Xiaohe Wang ◽  
Ya-Pu Zhao
Keyword(s):  
Machine Learning ◽  
Orbital Hybridization

scholarly journals Engineering d‐p Orbital Hybridization in Single‐Atom Metal‐Embedded Three‐Dimensional Electrodes for Li–S Batteries (Adv. Mater. 44/2021)

2021 ◽  
Vol 33 (44) ◽  
pp. 2170351
Author(s):  
Zhiyuan Han ◽  
Shiyong Zhao ◽  
Jiewen Xiao ◽  
Xiongwei Zhong ◽  
Jinzhi Sheng ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Single Atom ◽  
Orbital Hybridization

ChemInform Abstract: ORBITAL HYBRIDIZATION

1977 ◽  
Vol 8 (22) ◽  
pp. no-no
Author(s):  
B. KIRTMAN ◽  
D. M. CHIPMAN ◽  
W. E. PALKE
Keyword(s):  
Orbital Hybridization

P‐d orbital hybridization induced by monodispersed Ga site on Pt3Mn nanocatalyst boosts ethanol electrooxidation

2022 ◽  
Author(s):  
Yao Wang ◽  
Meng Zheng ◽  
Yunrui Li ◽  
Chenliang Ye ◽  
Juan Chen ◽  
...  
Keyword(s):  
Ethanol Electrooxidation ◽  
Orbital Hybridization
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