Solvation of ions. XVI. Solvent activity coefficients of single ions. Recommended extrathermodynamic assumption

1972 ◽  
Vol 94 (4) ◽  
pp. 1148-1158 ◽  
Author(s):  
R. Alexander ◽  
A. J. Parker ◽  
J. H. Sharp ◽  
W. E. Waghorne
Keyword(s):  
Activity Coefficients ◽  
Solvation Of Ions ◽  
Solvent Activity

Solvent activity coefficients at infinite dilution in polystyrene-hydrocarbon systems from inverse gas chromatography

1996 ◽  
Vol 13 (2) ◽  
pp. 129-135 ◽  
Author(s):  
Nam-Hyung Kim ◽  
Bong-Goo Choi ◽  
Joong-So Choi
Keyword(s):  
Gas Chromatography ◽  
Activity Coefficients ◽  
Infinite Dilution ◽  
Inverse Gas Chromatography ◽  
Solvent Activity

scholarly journals Standard Redox Potentials of R−/R+Reference Redox Couples and Solvent Activity Coefficients

1978 ◽  
Vol 51 (10) ◽  
pp. 2847-2854 ◽  
Author(s):  
Tadaaki Kakutani ◽  
Yoshikazu Morihiro ◽  
Mitsugi Senda ◽  
Reiji Takahashi ◽  
Koichi Matsumoto
Keyword(s):  
Activity Coefficients ◽  
Redox Potentials ◽  
Redox Couples ◽  
Solvent Activity

The possibility of determining the activity coefficients of individual ions from acid-base titration data

1998 ◽  
Vol 95 (7) ◽  
pp. 1583-1605 ◽  
Author(s):  
I. Jano ◽  
J. E. Hardcastle
Keyword(s):  
Activity Coefficients ◽  
Acid Base ◽  
Acid Base Titration ◽  
Titration Data

Solvation of ions by dipolar aprotic solvents and water. A CNDO/2 study

1985 ◽  
Vol 50 (11) ◽  
pp. 2493-2508 ◽  
Author(s):  
Petr Kyselka ◽  
Zdeněk Havlas ◽  
Ivo Sláma
Keyword(s):  
Binary Mixtures ◽  
Quantum Chemical ◽  
Chemical Method ◽  
Molecular Structures ◽  
Dimethyl Sulphoxide ◽  
Ternary Mixtures ◽  
Aprotic Solvents ◽  
Quantum Chemical Method ◽  
Solvation Of Ions ◽  
Dipolar Aprotic Solvents

Solvation of Li+, Be2+, Na+, Mg2+, and Al3+ ions has been studied in binary mixtures with dimethyl sulphoxide, dimethylformamide, acetonitrile and water, and in ternary mixtures of the organic solvents with water. The CNDO/2 quantum chemical method was used to calculate the energies of solvation, molecular structures and charge distributions for the complexes acetonitrile...ion (1:1, 2:1, 4:1), dimethyl sulphoxide...ion (1:1), dimethylformamide...ion (1:1), and acetonitrile (dimethyl sulphoxide, dimethylformamide)...ion...water (1:1:1).

Activity Coefficients and Gibbs Energies of Transfer of Tetraalkylammonium Dianilinetetraisothiocyanatochromates(III)

1994 ◽  
Vol 59 (8) ◽  
pp. 1738-1744
Author(s):  
Vladislav Holba
Keyword(s):  
Activity Coefficients ◽  
Transfer Functions ◽  
Butyl Alcohol ◽  
Methyl Ethyl ◽  
Tetraalkylammonium Ions ◽  
Ionic Transfer ◽  
Gibbs Energies ◽  
Gibbs Energies Of Transfer ◽  
Acetonitrile Solutions ◽  
Mixed Systems

The solubilities of tetraalkylammonium dianilinetetraisothiocyanatochromates(III) (alkyl = methyl, ethyl, 1-propyl, and 1-butyl) in water, water - methanol, water - tert-butyl alcohol and water - acetonitrile solutions were measured at 25 °C. The results were used to evaluate the activity coefficients and Gibbs energies of transfer of the saturating salts from water to the mixed systems. The Gibbs energies of transfer of the [Cr(C6H5NH2)2(NCS)4]- ion were obtained by means of known ionic transfer functions for the tetraalkylammonium ions based on the TATB assumption.

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