Octahedral Cobalt(III) Complexes in Dipolar Aprotic Solvents. IX.1Solvent Exchange of Some Dimethyl Sulfoxide Containing Bis (ethylenediamine) cobalt(III) Complexes and Solvent-Interchange Reactions of Somecis-Chloro (solvent) bis (ethylenediamine) cobalt(III) Ions and thetrans-Chloroaquobis (ethylenediamine) cobalt(III) Ion in Dimethyl Sulfoxide, N,N-Dimethylformanide, and N,N-Dimethylacetamide

1967 ◽  
Vol 89 (4) ◽  
pp. 815-821 ◽  
Author(s):  
I. R. Lantzke ◽  
D. W. Watts
Keyword(s):  
Dimethyl Sulfoxide ◽  
Aprotic Solvents ◽  
Dipolar Aprotic Solvents ◽  
Interchange Reactions

Solvation of the halide anions in dimethyl sulfoxide. Factors involved in enhanced reactivity of negative ions in dipolar aprotic solvents

1984 ◽  
Vol 106 (21) ◽  
pp. 6140-6146 ◽  
Author(s):  
Tom F. Magnera ◽  
Gary Caldwell ◽  
Jan Sunner ◽  
Sigeru Ikuta ◽  
Paul Kebarle
Keyword(s):  
Dimethyl Sulfoxide ◽  
Negative Ions ◽  
Aprotic Solvents ◽  
Halide Anions ◽  
Dipolar Aprotic Solvents

Electron-transfer reactions in non-aqueous media. VII. Reduction of CoF(NH3)52+ and Co(HCOO)(NH3)52+ by copper(I) in dimethyl sulfoxide-water mixtures

1983 ◽  
Vol 36 (10) ◽  
pp. 1923 ◽  
Author(s):  
JMB Harrowfield ◽  
L Spiccia ◽  
DW Watts
Keyword(s):  
Electron Transfer ◽  
Dimethyl Sulfoxide ◽  
Aqueous Media ◽  
Mixed Solvents ◽  
Transfer Reactions ◽  
Aprotic Solvents ◽  
Aqueous Mixtures ◽  
Electron Transfer Reactions ◽  
Dipolar Aprotic Solvents ◽  
Sphere Mechanism

Previous work on the reduction of a series of cobalt(III) complexes by iron(II) in dipolar aprotic solvents and in aqueous mixtures has been extended to reduction by copper(I). The greater stability of copper(I) to disproportionation in these media has permitted the study of the reduction of CoF(NH3)52+ and Co(HCOO)(NH3)52+ in range of solvents over a number of temperatures with a precision not possible in previous studies in water. The results are consistent with an inner-sphere mechanism in which the copper(I) reductant is preferentially solvated by dimethyl sulfoxide to the exclusion of water in mixed solvents.

Transfer activity coefficients between some dipolar aprotic solvents and alcohols of salts composed of various anions and potassium complexed with Bis(4,4'(5')-t-butylbenzo)-18-crown-6

1983 ◽  
Vol 36 (9) ◽  
pp. 1753 ◽  
Author(s):  
Jr MK Chantooni ◽  
IM Kolthoff ◽  
G Roland
Keyword(s):  
Dimethyl Sulfoxide ◽  
Stability Constants ◽  
Propylene Carbonate ◽  
Activity Coefficients ◽  
Isopropyl Alcohol ◽  
The Other ◽  
Aprotic Solvents ◽  
Transfer Activity ◽  
Dipolar Aprotic Solvents

Stability constants, Kf(LK+) and Kf(LKX) = [LKX]/[L][KX] at 25� in the dipolar aprotic solvents acetone (Me2CO), acetonitrile (MeCN), propylene carbonate (pc), N,N-dimethylformamide (HCONMe2), dimethyl sulfoxide (Me2SO), as well as in the alcohols, methanol (MeOH), isopropyl alcohol (Pr1OH), and butan -1-ol (BuOH) have been determined, L being bis(4,4'(5')-t-buty1benzo)-18- crown-6 (di(BuBo)-18-cr-6). This crown is considerably more lipophylic than is dibenzo-18-crown-6. Values of Kf(LKX) have been found from values of Kf(LK+), KA(KX) and KA(LKX). Transfer activity coefficients, Me2COγS, have been calculated (based on the Parker proposal that γ(Ph4As+) = γ(BPh4-) between acetone and the various solvents used of K+, Br-, ClO4-, P1- (picrate), LK+, KX, and LKX. It is found that K+ is more strongly solvated in Me2CO than in the other aprotic solvents of low donicity. The reverse is true between Me2CO and HCONMe2 or Me2SO (even after correcting for the Born effect).

Acceptor Numbers for Binary Mixtures of Dipolar Aprotic Solvents with Methanol

1994 ◽  
Vol 59 (6) ◽  
pp. 1349-1355 ◽  
Author(s):  
Malgorzata Podsiadla ◽  
Jadwiga Rzeszotarska ◽  
Marek K. Kalinowski
Keyword(s):  
Dimethyl Sulfoxide ◽  
Binary Mixtures ◽  
Preferential Solvation ◽  
Molar Fraction ◽  
Liquid Structure ◽  
Aprotic Solvents ◽  
Hexamethylphosphoric Triamide ◽  
Acceptor Numbers ◽  
Dipolar Aprotic Solvents

Using bis(cyano)bis(9,10-phenanthroline)iron(II) as solvatochromic indicator, the acceptor numbers, AN, were determined for binary mixtures of benzene, benzonitrile, acetonitrile, acetone, N,N-dimethylformamide, dimethyl sulfoxide and hexamethylphosphoric triamide with methanol. Deviations from linearity of the plots of AN values against the molar fraction of the components were interpreted both in terms of changes in solvent liquid structure and in cathegories of preferential solvation.

Donor Numbers for Binary Mixtures of Dimethyl Sulfoxide with Dipolar Aprotic Solvents

1994 ◽  
Vol 59 (10) ◽  
pp. 2201-2208 ◽  
Author(s):  
Jadwiga Rzeszotarska ◽  
Przemyslaw Ranachowski ◽  
Marek K. Kalinowski
Keyword(s):  
Solvent Effect ◽  
Dimethyl Sulfoxide ◽  
Binary Mixtures ◽  
Mixed Solvent ◽  
Aprotic Solvents ◽  
Visible Absorption ◽  
Stability Constants Of Complexes ◽  
Donor Numbers ◽  
The Stability ◽  
Dipolar Aprotic Solvents

Solvent effect on the visible absorption spectrum of (acetylacetonato)(N,N,N',N'-tetramethylethylene-diamine)copper(II) was applied to estimate DN, the donor numbers of the binary mixtures of dimethyl sulfoxide with a series of other dipolar aprotic solvents. It was found that resulting DN values may be treated as explanatory parameters in the description of the mixed solvent effect on the stability constants of complexes formed by some macrocyclic ligands with univalent cations.

Nucleophilic Substitution Reactions of Thienyl Neopentyl Substrates

1987 ◽  
Vol 40 (1) ◽  
pp. 49 ◽  
Author(s):  
FI Mclure ◽  
RK Norris ◽  
K Wilson
Keyword(s):  
Dimethyl Sulfoxide ◽  
Nucleophilic Substitution ◽  
Aprotic Solvents ◽  
Substitution Reactions ◽  
Nucleophilic Substitution Reactions ◽  
Benzene Series ◽  
Dipolar Aprotic Solvents

The reaction of the chlorides (4)-(6), which are both neopentylic and thenylic , were studied. The chloride (4), unlike its analogue (13) in the benzene series, undergoes ready solvolysis with alcohols to give the corresponding ethers, e.g. (7)-(9). The chlorides (5) and (6) react more slowly than (4) but undergo methanolysis to give the methyl ethers (11) and (12) respectively. In the dipolar aprotic solvents, dimethyl sulfoxide and dimethylformamide, the reactions of the chlorides (4), (5) and (6) with the thiolate salt (16) appear to proceed by an SN1-like, an SN(AEAE) and an SRNl process respectively.

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