Kinetics of the Dissociation of Weak Acids and Bases—Application of Polarography and Voltammetry at Constant Current

1955 ◽  
Vol 77 (19) ◽  
pp. 4955-4958 ◽  
Author(s):  
Paul Delahay ◽  
Wolf Vielstich
1998 ◽  
Vol 536 ◽  
Author(s):  
E. M. Wong ◽  
J. E. Bonevich ◽  
P. C. Searson

AbstractColloidal chemistry techniques were used to synthesize ZnO particles in the nanometer size regime. The particle aging kinetics were determined by monitoring the optical band edge absorption and using the effective mass model to approximate the particle size as a function of time. We show that the growth kinetics of the ZnO particles follow the Lifshitz, Slyozov, Wagner theory for Ostwald ripening. In this model, the higher curvature and hence chemical potential of smaller particles provides a driving force for dissolution. The larger particles continue to grow by diffusion limited transport of species dissolved in solution. Thin films were fabricated by constant current electrophoretic deposition (EPD) of the ZnO quantum particles from these colloidal suspensions. All the films exhibited a blue shift relative to the characteristic green emission associated with bulk ZnO. The optical characteristics of the particles in the colloidal suspensions were found to translate to the films.


1994 ◽  
Vol 19 (1-2) ◽  
pp. 173-188 ◽  
Author(s):  
W. Winiwarter ◽  
H. Fierlinger ◽  
H. Puxbaum ◽  
M. C. Facchini ◽  
B. G. Arends ◽  
...  

2005 ◽  
Vol 123 (16) ◽  
pp. 164510 ◽  
Author(s):  
Kristóf Iván ◽  
Mária Wittmann ◽  
Péter L. Simon ◽  
Zoltán Noszticzius ◽  
Dalimil Šnita

1979 ◽  
Vol 56 (12) ◽  
pp. 814
Author(s):  
Joseph C. Deck
Keyword(s):  

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