The Heats of Solution, Heats of Formation, Specific Heats and Equilibrium Diagrams of Certain Molecular Compounds

1940 ◽  
Vol 62 (2) ◽  
pp. 291-297 ◽  
Author(s):  
A. N. Campbell ◽  
A. J. R. Campbell
Keyword(s):  
Heats Of Formation ◽  
Specific Heats ◽  
Heats Of Solution ◽  
Molecular Compounds ◽  
Formation Specific

Heats of formation of zirconium hydrides

1964 ◽  
Vol 17 (10) ◽  
pp. 1063 ◽  
Author(s):  
AG Turnbull
Keyword(s):  
Heat Capacity ◽  
Thermodynamic Properties ◽  
Heats Of Formation ◽  
Kcal Mole ◽  
Dissociation Pressure ◽  
Heats Of Solution ◽  
Zirconium Hydrides ◽  
Zirconium Metal

Heats of solution in 3.83N HF have been measured for zirconium metal and for five zirconium hydrides to evaluate the following heats of formation AHf0298: ZrH2 -39.7, ZrH1.85 -38.2, ZrH1.70. -34.7, ZrH1.43 -30.05, ZrH1.23 -25.3 kcal/mole hydride. A review of heat capacity and entropy data for zirconium hydrides has enabled a good correlation to be made between calorimetric and dissociation pressure studies, so that the effect of composition on all thermodynamic properties is established.

THE HEATS OF SOLUTION AND SPECIFIC HEATS OF RHOMBIC SULPHUR IN CARBON DISULPHIDE: THE SURFACE ENERGY OF SOLID RHOMBIC SULPHUR

1935 ◽  
Vol 13b (5) ◽  
pp. 280-288 ◽  
Author(s):  
A. R. Williams ◽  
F. M. G. Johnson ◽  
O. Maass
Keyword(s):  
Particle Size ◽  
Surface Energy ◽  
Carbon Disulphide ◽  
Heat Of Solution ◽  
Specific Heats ◽  
Heats Of Solution

The heats of solution of rhombic sulphur in carbon disulphide were measured over the concentration range 6 to 17% of sulphur and at 20° and 25 °C., and the specific heats of these solutions were calculated. The apparatus designed for these measurements is described. By measuring the heat of solution of finely divided sulphur and its particle size, the surface energy of solid rhombic sulphur is estimated.

Heats of Solution and Swelling of Some Synthetic High-Molecular Compounds

1951 ◽  
Vol 24 (4) ◽  
pp. 773-776 ◽  
Author(s):  
A. Tager ◽  
V. Sanatina
Keyword(s):  
Mechanical Behavior ◽  
Polymer Chain ◽  
High Polymer ◽  
Heat Of Solution ◽  
Barrier Potential ◽  
Heats Of Solution ◽  
Molecular Compounds

Abstract 1. The heat of solution of a high polymer depends on the nature of the solvent as well as on the nature of the polymer. 2. The value and sign of the heat of solution of a polymer are related to the structure of the polymer and its mechanical behavior. For polymers which have relatively flexible chains, the heats of solution are negative ; for polymers which have relatively rigid chains, the heats of solution are positive. 3. The value and sign of the heat of solution indicate to a certain degree the change of the barrier potential of the polymer chain in any given solvent.

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