Dramatic Acceleration of Olefin Epoxidation in Fluorinated Alcohols:  Activation of Hydrogen Peroxide by Multiple H-Bond Networks

2006 ◽  
Vol 128 (41) ◽  
pp. 13412-13420 ◽  
Author(s):  
Albrecht Berkessel ◽  
Jens A. Adrio
Keyword(s):  
Hydrogen Peroxide ◽  
Olefin Epoxidation ◽  
Fluorinated Alcohols ◽  
Activation Of Hydrogen Peroxide

Selective Cyclohexene Oxidation to Allylic Compounds over Cu-triazole Framework via Homolytic Activation of Hydrogen Peroxide

2021 ◽  
Author(s):  
Panyapat Ponchai ◽  
Kanyaporn Adpakpang ◽  
Sareeya Bureekaew
Keyword(s):  
Hydrogen Peroxide ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Porous Structures ◽  
Cyclohexene Oxidation ◽  
Catalytic Sites ◽  
P Utilization ◽  
Metal Organic ◽  
Activation Of Hydrogen Peroxide

Utilization of metal-organic frameworks as heterogeneous catalysts is crucial owing to their abundant catalytic sites and well-defined porous structures. Highly robust [Cu3(trz)3(μ3-OH)(OH)2(H2O)4]∙2H2O (trz = 1,2,4-triazole) was employed as a catalyst...

Farringtonite as an efficient catalyst for linear-chain α-olefin epoxidation with aqueous hydrogen peroxide

2021 ◽  
Author(s):  
Xingyu Yang ◽  
Xu Li ◽  
Jinxiang Dong
Keyword(s):  
Hydrogen Peroxide ◽  
Transition Metals ◽  
Linear Chain ◽  
Olefin Epoxidation ◽  
Aqueous Hydrogen Peroxide ◽  
Efficient Catalyst ◽  
First Time

A convenient, scalable, benign, and efficient epoxidation method based on farringtonite, without the use of transition metals, was developed for the first time.

Protons Make Possible Heterolytic Activation of Hydrogen Peroxide over Zr-Based Metal–Organic Frameworks

ACS Catalysis ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 9699-9704 ◽  
Author(s):  
Nataliya V. Maksimchuk ◽  
Ji Sun Lee ◽  
Marina V. Solovyeva ◽  
Kyung Ho Cho ◽  
Aleksandr N. Shmakov ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Activation Of Hydrogen Peroxide
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