Gas Phase Photochemical Synthesis of II/VI Metal Sulfide Films andin SituLuminescence Spectroscopic Identification of Photofragments

1997 ◽  
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Author(s):  
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Jeffrey I. Zink

1976 ◽  
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Author(s):  
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Richard C. Noonan ◽  
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Philip L. Hanst


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1963 ◽  
Vol 7 (1) ◽  
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ChemInform ◽  
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Vol 27 (25) ◽  
pp. no-no
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M. YI


2016 ◽  
Vol 612 ◽  
pp. 208-213 ◽  
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C. Detavernier


2018 ◽  
Vol 115 (23) ◽  
pp. 5866-5871 ◽  
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Maximilian Joost ◽  
Matthew Nava ◽  
Wesley J. Transue ◽  
Marie-Aline Martin-Drumel ◽  
Michael C. McCarthy ◽  
...  

Sulfur monoxide (SO) is a highly reactive molecule and thus, eludes bulk isolation. We report here on synthesis and reactivity of a molecular precursor for SO generation, namely 7-sulfinylamino-7-azadibenzonorbornadiene (1). This compound has been shown to fragment readily driven by dinitrogen expulsion and anthracene formation on heating in the solid state and in solution, releasing SO at mild temperatures (<100 °C). The generated SO was detected in the gas phase by MS and rotational spectroscopy. In solution, 1 allows for SO transfer to organic molecules as well as transition metal complexes.



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