M(dmit)2Salts with Nitronyl Nitroxide Radical Cations (M = Ni and Au, dmit = 1,3-Dithiol-2-thione-4,5-dithiolate). Nonmagnetic Single-Chain Formation vs Antiferromagnetic Spin-Ladder-Chain Formation of M(dmit)2

A minor change of the site of the substituent on the nitronyl nitroxide radical significantly influences the magnetization dynamics of two single-chain magnets, due to the influence of both the magnetic anisotropies of the TbIII centers and magnetic couplings along the chains.

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Lanthanide chains containing the naphthalenyl nitronyl nitroxide radical

RSC Advances ◽

10.1039/c9ra06506g ◽

2019 ◽

Vol 9 (52) ◽

pp. 30302-30308 ◽

Cited By ~ 2

Author(s):

Charlie V. Sarmiento ◽

Thamyres A. Araujo ◽

Samira G. Reis ◽

Mateus S. de Souza ◽

Rafael A. Allão Cassaro ◽

...

Keyword(s):

Nitroxide Radical ◽

Nitronyl Nitroxide ◽

Single Chain ◽

Nitronyl Nitroxide Radical

Three lanthanide(iii)–nitronil nitroxide chains containing polyaromatic naphthalenyl substituents have been synthesized and characterized. The dysprosium and terbium chains show single-chain magnet behavior.

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Multifunctional properties existing in Ln–nitronyl nitroxide single-chain magnets

Journal of Materials Chemistry C ◽

10.1039/d0tc04266h ◽

2021 ◽

Vol 9 (1) ◽

pp. 294-302

Author(s):

Hongdao Li ◽

Lu Xi ◽

Pei Jing ◽

Jianke Tang ◽

Qi Wang ◽

...

Keyword(s):

Magnetic Properties ◽

Nitroxide Radical ◽

Nitronyl Nitroxide ◽

Single Chain ◽

Nitronyl Nitroxide Radical ◽

One Dimensional ◽

System P ◽

Optical Behavior ◽

Single Chain Magnets ◽

Multifunctional Properties

Two Ln–radical one-dimensional chains have been isolated via a quinoline nitronyl nitroxide radical and the magnetic properties, thermodynamics and optical behavior of compounds were observed, exhibiting polyfunctionality of the 2p–4f system.

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Ferromagnetic interaction between nitronyl nitroxide radical cations in a semiconducting salt

Synthetic Metals ◽

10.1016/s0379-6779(97)80403-1 ◽

1997 ◽

Vol 85 (1-3) ◽

pp. 1705-1706 ◽

Cited By ~ 3

Author(s):

H. Imai ◽

T. Inabe ◽

T. Otsuka ◽

T. Okuno ◽

K. Awaga

Keyword(s):

Nitroxide Radical ◽

Radical Cations ◽

Nitronyl Nitroxide ◽

Nitronyl Nitroxide Radical ◽

Ferromagnetic Interaction

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Multifunctional properties of {CuII2LnIII2} systems involving nitrogen-rich nitronyl nitroxide: single-molecule magnet behavior, luminescence, magnetocaloric effects and heat capacity

Dalton Transactions ◽

10.1039/d0dt04344c ◽

2021 ◽

Author(s):

Hongdao Li ◽

Pei Jing ◽

Jiao Lu ◽

Lu Xi ◽

Qi Wang ◽

...

Keyword(s):

Heat Capacity ◽

Magnetic Properties ◽

Single Molecule ◽

Nitroxide Radical ◽

Nitronyl Nitroxide ◽

Nitronyl Nitroxide Radical ◽

Single Molecule Magnet ◽

Luminescence Behavior ◽

Multifunctional Properties

A family of 3d–4f heterometallic ring-shaped clusters on the basis of a nitrogen-rich nitronyl nitroxide radical have been obtained, and they feature polyfunctionality including magnetic properties, thermodynamics and luminescence behavior.

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