Tuning the magnetization dynamics of TbIII-based single-chain magnets through substitution on the nitronyl nitroxide radical

2019 ◽  
Vol 48 (24) ◽  
pp. 8989-8994 ◽  
Author(s):  
Xiaoqing Liu ◽  
Yu-Xia Wang ◽  
Zongsu Han ◽  
Tian Han ◽  
Wei Shi ◽  
...  
Keyword(s):  
Nitroxide Radical ◽  
Nitronyl Nitroxide ◽  
Single Chain ◽  
Magnetization Dynamics ◽  
Nitronyl Nitroxide Radical ◽  
Magnetic Couplings ◽  
A Minor ◽  
Single Chain Magnets

A minor change of the site of the substituent on the nitronyl nitroxide radical significantly influences the magnetization dynamics of two single-chain magnets, due to the influence of both the magnetic anisotropies of the TbIII centers and magnetic couplings along the chains.

Multifunctional properties existing in Ln–nitronyl nitroxide single-chain magnets

2021 ◽  
Vol 9 (1) ◽  
pp. 294-302
Author(s):  
Hongdao Li ◽  
Lu Xi ◽  
Pei Jing ◽  
Jianke Tang ◽  
Qi Wang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Nitroxide Radical ◽  
Nitronyl Nitroxide ◽  
Single Chain ◽  
Nitronyl Nitroxide Radical ◽  
One Dimensional ◽  
System P ◽  
Optical Behavior ◽  
Single Chain Magnets ◽  
Multifunctional Properties

Two Ln–radical one-dimensional chains have been isolated via a quinoline nitronyl nitroxide radical and the magnetic properties, thermodynamics and optical behavior of compounds were observed, exhibiting polyfunctionality of the 2p–4f system.

scholarly journals Lanthanide chains containing the naphthalenyl nitronyl nitroxide radical

RSC Advances ◽  
2019 ◽  
Vol 9 (52) ◽  
pp. 30302-30308 ◽  
Author(s):  
Charlie V. Sarmiento ◽  
Thamyres A. Araujo ◽  
Samira G. Reis ◽  
Mateus S. de Souza ◽  
Rafael A. Allão Cassaro ◽  
...  
Keyword(s):  
Nitroxide Radical ◽  
Nitronyl Nitroxide ◽  
Single Chain ◽  
Nitronyl Nitroxide Radical

Three lanthanide(iii)–nitronil nitroxide chains containing polyaromatic naphthalenyl substituents have been synthesized and characterized. The dysprosium and terbium chains show single-chain magnet behavior.

Multifunctional properties of {CuII2LnIII2} systems involving nitrogen-rich nitronyl nitroxide: single-molecule magnet behavior, luminescence, magnetocaloric effects and heat capacity

2021 ◽  
Author(s):  
Hongdao Li ◽  
Pei Jing ◽  
Jiao Lu ◽  
Lu Xi ◽  
Qi Wang ◽  
...  
Keyword(s):  
Heat Capacity ◽  
Magnetic Properties ◽  
Single Molecule ◽  
Nitroxide Radical ◽  
Nitronyl Nitroxide ◽  
Nitronyl Nitroxide Radical ◽  
Single Molecule Magnet ◽  
Luminescence Behavior ◽  
Multifunctional Properties

A family of 3d–4f heterometallic ring-shaped clusters on the basis of a nitrogen-rich nitronyl nitroxide radical have been obtained, and they feature polyfunctionality including magnetic properties, thermodynamics and luminescence behavior.

One-dimensional magnetism of a linear chain compound containing yttrium(III) and a nitronyl nitroxide radical

1989 ◽  
Vol 28 (16) ◽  
pp. 3230-3234 ◽  
Author(s):  
Cristiano Benelli ◽  
Andrea Caneschi ◽  
Dante Gatteschi ◽  
Luca Pardi ◽  
Paul Rey
Keyword(s):  
Linear Chain ◽  
Nitroxide Radical ◽  
Nitronyl Nitroxide ◽  
Nitronyl Nitroxide Radical ◽  
One Dimensional ◽  
Chain Compound

Crystal Packing Effects on the Magnetic Slow Relaxation of Tb(III)-Nitronyl Nitroxide Radical Cyclic Dinuclear Clusters

2012 ◽  
Vol 51 (22) ◽  
pp. 12218-12229 ◽  
Author(s):  
Fabrice Pointillart ◽  
Kevin Bernot ◽  
Giordano Poneti ◽  
Roberta Sessoli
Keyword(s):  
Crystal Packing ◽  
Nitroxide Radical ◽  
Slow Relaxation ◽  
Nitronyl Nitroxide ◽  
Nitronyl Nitroxide Radical ◽  
Crystal Packing Effects ◽  
Packing Effects

Syntheses, Crystal Structures, and Magnetic Properties of Two Mononuclear Nickel-Nitronyl Nitroxide Radical Compounds

2016 ◽  
Vol 642 (7) ◽  
pp. 527-531 ◽  
Author(s):  
Bin Zhai ◽  
Zhong-Yi Li ◽  
Fu-Qiang Zhang ◽  
Su-Zhi Li ◽  
Fu-Li Zhang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Nitroxide Radical ◽  
Nitronyl Nitroxide ◽  
Nitronyl Nitroxide Radical

scholarly journals Chemisorption of nitronyl-nitroxide radicals on gold surface: an assessment of morphology, exchange interaction and decoherence time.

Nanoscale ◽  
2021 ◽  
Author(s):  
Lorenzo Poggini ◽  
Alessandro Lunghi ◽  
Alberto Collauto ◽  
Antonio Barbon ◽  
Lidia Armelao ◽  
...  
Keyword(s):  
Exchange Interaction ◽  
Nitroxide Radical ◽  
Gold Surface ◽  
Nitronyl Nitroxide ◽  
Nitroxide Radicals ◽  
Nitronyl Nitroxide Radical ◽  
Decoherence Time ◽  
Tof Sims

A combined Tof-SIMS, XPS and STM characterization has been adopted here to study the deposition of a sulphur-functionalized nitronyl nitroxide radical on Au(111) clearly demonstrating the chemisorption of intact molecules....

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