Systematic Trends in the Electrochemical Properties of Transition Metal Hydride Complexes Discovered by Using the Ligand Acidity Constant Equation

2020 ◽  
Vol 142 (41) ◽  
pp. 17607-17629 ◽  
Author(s):  
Benjamin E. Rennie ◽  
Renée G. Eleftheriades ◽  
Robert H. Morris
Keyword(s):  
Transition Metal ◽  
Electrochemical Properties ◽  
Metal Hydride ◽  
Acidity Constant ◽  
Hydride Complexes ◽  
Transition Metal Hydride

DFT methods applied to answer the question: how accurate is the ligand acidity constant method for estimating the pKa of transition metal hydride complexes MHXL4 when X is varied?

2018 ◽  
Vol 47 (8) ◽  
pp. 2739-2747 ◽  
Author(s):  
Jan P. Unsleber ◽  
Johannes Neugebauer ◽  
Robert H. Morris
Keyword(s):  
Transition Metal ◽  
Metal Hydride ◽  
Acidity Constant ◽  
Acidity Constants ◽  
Dft Methods ◽  
Hydride Complexes ◽  
Anionic Ligands ◽  
Transition Metal Hydride

Additive ligand acidity constants AL of anionic ligands are calculated for neutral hydrides of iron(ii), ruthenium(ii) and osmium(ii) with phosphine and carbonyl co-ligands; constant AL in green, more variable AL in red.

ChemInform Abstract: STRUCTURES OF TRANSITION-METAL HYDRIDE COMPLEXES

1979 ◽  
Vol 10 (40) ◽  
Author(s):  
R. BAU ◽  
R. G. TELLER ◽  
S. W. KIRTLEY ◽  
T. F. KOETZLE
Keyword(s):  
Transition Metal ◽  
Metal Hydride ◽  
Hydride Complexes ◽  
Transition Metal Hydride

Bimetallic Transition Metal Hydride Complexes

1983 ◽  
Vol 52 (1) ◽  
pp. 43-60 ◽  
Author(s):  
Grigorii L Soloveichik ◽  
Boris M Bulychev
Keyword(s):  
Transition Metal ◽  
Metal Hydride ◽  
Hydride Complexes ◽  
Transition Metal Hydride
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