Ligand Field Inversion as a Mechanism to Gate Bioorganometallic Reactivity: Investigating a Biochemical Model of Acetyl CoA Synthase Using Spectroscopy and Computation

2021 ◽  
Vol 143 (2) ◽  
pp. 849-867
Author(s):  
Effie C. Kisgeropoulos ◽  
Anastasia C. Manesis ◽  
Hannah S. Shafaat
Keyword(s):  
Ligand Field ◽  
Acetyl Coa ◽  
Biochemical Model ◽  
Field Inversion

Spectroscopic Evidence for a 3d10 Ground State Electronic Configuration and Ligand Field Inversion in [Cu(CF3)4]1–

2016 ◽  
Vol 138 (6) ◽  
pp. 1922-1931 ◽  
Author(s):  
Richard C. Walroth ◽  
James T. Lukens ◽  
Samantha N. MacMillan ◽  
Kenneth D. Finkelstein ◽  
Kyle M. Lancaster
Keyword(s):  
Ground State ◽  
Electronic Configuration ◽  
Ligand Field ◽  
Spectroscopic Evidence ◽  
Field Inversion

Molecular oxofluorides OMFn of nickel, palladium and platinum: oxyl radicals with moderate ligand field inversion

2021 ◽  
Author(s):  
Lin Li ◽  
Helmut Beckers ◽  
Tony Stüker ◽  
Tilen Lindič ◽  
Tobias Schlöder ◽  
...  
Keyword(s):  
Transition Metal ◽  
Ligand Field ◽  
Late Transition Metal ◽  
Late Transition ◽  
Oxo Compounds ◽  
High Valent ◽  
Oxygen Bond ◽  
Field Inversion ◽  
Oxo Ligands

High-valent late transition metal oxo compounds attracted attention because of their peculiar metal–oxygen bond. Their oxo ligands exhibit an electrophilic and distinct radical oxyl (O˙−) rather than the more common nucleophilic (O2−) character.

scholarly journals Hydrogen bonding to metals as a probe for an inverted ligand field

2021 ◽  
Vol 50 (16) ◽  
pp. 5465-5472
Author(s):  
Alberto Pérez-Bitrián ◽  
Miguel Baya ◽  
José M. Casas ◽  
Antonio Martín ◽  
Babil Menjón
Keyword(s):  
Hydrogen Bonding ◽  
Ligand Field ◽  
Square Planar ◽  
Axial Interaction ◽  
Field Inversion

The M⋯HO axial interaction in the isoleptic and isoelectronic square-planar compounds [(CF3)3Pt(hq)]− and (CF3)3Au(hq) turns from attractive (M = Pt) to repulsive (M = Au), evidencing ligand-field inversion when going from Pt to Au.

The role of rice bran extract on acetyl CoA carboxylase in liver of rats fed a high-fat diet

Planta Medica ◽  
2011 ◽  
Vol 77 (12) ◽  
Author(s):  
C Charkhonpunya ◽  
S Sireeratawong ◽  
S Komindr ◽  
N Lerdvuthisopon
Keyword(s):  
Rice Bran ◽  
High Fat Diet ◽  
Acetyl Coa Carboxylase ◽  
High Fat ◽  
Acetyl Coa ◽  
Rice Bran Extract

Ligand Field Studies on the Reinecke-Type Complexes with Aniline and Benzylamine

1971 ◽  
Vol 74 (1_2) ◽  
pp. 11-16 ◽  
Author(s):  
I. Gănescu ◽  
Margareta Teodorescu ◽  
C. I. Lepădatu
Keyword(s):  
Field Studies ◽  
Ligand Field
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