Systematic and Dramatic Tuning on Gas Sorption Performance in Heterometallic Metal–Organic Frameworks

2016 ◽  
Vol 138 (8) ◽  
pp. 2524-2527 ◽  
Author(s):  
Quan-Guo Zhai ◽  
Xianhui Bu ◽  
Chengyu Mao ◽  
Xiang Zhao ◽  
Pingyun Feng
Keyword(s):  
Metal Organic Frameworks ◽  
Gas Sorption ◽  
Metal Organic

scholarly journals A combined experimental and theoretical study of gas sorption on nanoporous silver triazolato metal–organic frameworks

2014 ◽  
Vol 183 ◽  
pp. 62-68 ◽  
Author(s):  
Guang Yang ◽  
Juan A. Santana ◽  
Milton E. Rivera-Ramos ◽  
Omar García-Ricard ◽  
Jose J. Saavedra-Arias ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Metal Organic Frameworks ◽  
Gas Sorption ◽  
Metal Organic

High Gas Sorption and Metal-Ion Exchange of Microporous Metal-Organic Frameworks with Incorporated Imide Groups

2010 ◽  
Vol 16 (47) ◽  
pp. 14043-14050 ◽  
Author(s):  
Thazhe Kootteri Prasad ◽  
Dae Ho Hong ◽  
Myunghyun Paik Suh
Keyword(s):  
Ion Exchange ◽  
Metal Ion ◽  
Metal Organic Frameworks ◽  
Gas Sorption ◽  
Metal Organic ◽  
Metal Ion Exchange

Ti4(embonate)6 Cage-Ligand Strategy on the Construction of Metal–Organic Frameworks with High Stability and Gas Sorption Properties

2020 ◽  
Vol 59 (2) ◽  
pp. 964-967 ◽  
Author(s):  
Yan-Ping He ◽  
Guang-Hui Chen ◽  
Lv-Bing Yuan ◽  
Lei Zhang ◽  
Jian Zhang
Keyword(s):  
High Stability ◽  
Metal Organic Frameworks ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Metal Organic

Two cationic metal–organic frameworks featuring different cage-to-cage connections: syntheses, crystal structures, photoluminescence and gas sorption properties

CrystEngComm ◽  
2013 ◽  
Vol 15 (40) ◽  
pp. 8139 ◽  
Author(s):  
Zhen-Zhen Xue ◽  
Tian-Lu Sheng ◽  
Qi-Long Zhu ◽  
Da-Qiang Yuan ◽  
Yan-Long Wang ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Metal Organic Frameworks ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Metal Organic

Isostructural Ni II Metal–Organic Frameworks (MOFs) for Efficient Electrocatalysis of Oxygen Evolution Reaction and for Gas Sorption Properties

2019 ◽  
Vol 25 (47) ◽  
pp. 11141-11146 ◽  
Author(s):  
Satyanarayana K. Konavarapu ◽  
Debanjali Ghosh ◽  
Avishek Dey ◽  
Debabrata Pradhan ◽  
Kumar Biradha
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Metal Organic Frameworks ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Metal Organic

scholarly journals Increasing the Stability of Metal-Organic Frameworks

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Mathieu Bosch ◽  
Muwei Zhang ◽  
Hong-Cai Zhou
Keyword(s):  
Metal Organic Frameworks ◽  
Luminescent Properties ◽  
Vacuum Treatment ◽  
Donor Ligands ◽  
Gas Sorption ◽  
Nitrogen Donor Ligands ◽  
Metal Centers ◽  
Ligand Interactions ◽  
Metal Organic ◽  
The Stability

Metal-organic frameworks (MOFs) are a new category of advanced porous materials undergoing study by many researchers for their vast variety of both novel structures and potentially useful properties arising from them. Their high porosities, tunable structures, and convenient process of introducing both customizable functional groups and unsaturated metal centers have afforded excellent gas sorption and separation ability, catalytic activity, luminescent properties, and more. However, the robustness and reactivity of a given framework are largely dependent on its metal-ligand interactions, where the metal-containing clusters are often vulnerable to ligand substitution by water or other nucleophiles, meaning that the frameworks may collapse upon exposure even to moist air. Other frameworks may collapse upon thermal or vacuum treatment or simply over time. This instability limits the practical uses of many MOFs. In order to further enhance the stability of the framework, many different approaches, such as the utilization of high-valence metal ions or nitrogen-donor ligands, were recently investigated. This review details the efforts of both our research group and others to synthesize MOFs possessing drastically increased chemical and thermal stability, in addition to exemplary performance for catalysis, gas sorption, and separation.

Two Robust Porous Metal-Organic Frameworks Sustained by Distinct Catenation: Selective Gas Sorption and Single-Crystal-to-Single-Crystal Guest Exchange

2010 ◽  
Vol 5 (11) ◽  
pp. 2358-2368 ◽  
Author(s):  
Rui Yang ◽  
Lei Li ◽  
Ying Xiong ◽  
Jian-Rong Li ◽  
Hong-Cai Zhou ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Gas Sorption ◽  
Metal Organic
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