Measurements of the Speed of Sound and Density of Aqueous Solutions of the First-Row Transition Metal Halides. 3. Apparent Molar Compressibilities and Volumes of Aqueous CoI2and NiI2within the Temperature Range 291.15 K to 297.15 K

2000 ◽  
Vol 45 (6) ◽  
pp. 1064-1068 ◽  
Author(s):  
Stefan Ernst ◽  
Monika Gepert ◽  
Robert Manikowski
Keyword(s):  
Transition Metal ◽  
Aqueous Solutions ◽  
Speed Of Sound ◽  
Metal Halides ◽  
Temperature Range ◽  
Apparent Molar Compressibilities

Ion solvation of aqueous solutions of alkali, alkaline earth, and transition metal halides

2012 ◽  
Vol 53 (5) ◽  
pp. 892-901 ◽  
Author(s):  
V. N. Afanas’ev ◽  
A. N. Ustinov
Keyword(s):  
Transition Metal ◽  
Aqueous Solutions ◽  
Alkaline Earth ◽  
Ion Solvation ◽  
Metal Halides

The Effect of γ-Al2O3, TiO2 and ZrO2 Supports on Hydrodesulfurization Activity of Transition-Metal Sulfides

2008 ◽  
Vol 73 (8-9) ◽  
pp. 945-955 ◽  
Author(s):  
Luděk Kaluža ◽  
Miroslav Zdražil
Keyword(s):  
Transition Metal ◽  
Aqueous Solutions ◽  
Model Reaction ◽  
Metal Sulfides ◽  
Vacuum Impregnation ◽  
Transition Metal Sulfides ◽  
Highly Active ◽  
System A ◽  
Benzothiophene Hydrodesulfurization ◽  
Hydrodesulfurization Activity

The transition metals V, Cr, Mn, Fe, Co, Ni, Mo, Ru, Rh, Pd, W, Re, Os, Ir and Pt were deposited from aqueous solutions of their salts onto conventional γ-Al2O3 and unconventional TiO2 and ZrO2 supports by vacuum impregnation and characterized in their sulfided form by a model reaction of benzothiophene hydrodesulfurization. It was found that the TiO2 and ZrO2 supports influenced predominantly positively the resulting activity of relatively low-active metals (V, Cr, Mn, Fe, Co, Ni, Mo, Ru, W and Os), whereas the highly active metals (Rh, Pd, Ir, Pt and Re) were influenced slightly negatively or not at all by those supports compared with the γ-Al2O3-supported system. A significant effect of the supports on the hydrodesulfurization-activity ranking of the transition-metal sulfides studied was ascertained.

scholarly journals Early-stage formation of (hydr)oxo bridges in transition-metal catalysts for photosynthetic processes

2021 ◽  
Author(s):  
Shin Nakamura ◽  
Matteo Capone ◽  
Giuseppe Mattioli ◽  
Leonardo Guidoni
Keyword(s):  
Transition Metal ◽  
Aqueous Solutions ◽  
Ab Initio ◽  
Early Stage ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Electrochemical Potential ◽  
Ab Initio Simulations

Water-oxidizing metal-(hydr)oxo catalyst films can be generally deposited and activated by applying a positive electrochemical potential to suitable starting aqueous solutions. Here, we used ab initio simulations based on density...

ChemInform Abstract: Interstitial Hydrogen in the Early-Transition-Metal Halides.

ChemInform ◽  
1987 ◽  
Vol 18 (39) ◽  
Author(s):  
J. K. BURDETT ◽  
G. J. MILLER
Keyword(s):  
Transition Metal ◽  
Metal Halides ◽  
Early Transition Metal ◽  
Interstitial Hydrogen ◽  
Early Transition

Interstitial hydrogen in the early transition-metal halides

1987 ◽  
Vol 109 (13) ◽  
pp. 4092-4104 ◽  
Author(s):  
Jeremy K. Burdett ◽  
Gordon J. Miller
Keyword(s):  
Transition Metal ◽  
Metal Halides ◽  
Early Transition Metal ◽  
Interstitial Hydrogen ◽  
Early Transition

Molecular Dynamics Investigation of Dipeptide - Transition Metal Salts in Aqueous Solutions

2010 ◽  
Vol 114 (49) ◽  
pp. 16632-16640 ◽  
Author(s):  
M. S. Santosh ◽  
Alexander P. Lyubartsev ◽  
Alexander A. Mirzoev ◽  
D. Krishna Bhat
Keyword(s):  
Molecular Dynamics ◽  
Transition Metal ◽  
Aqueous Solutions ◽  
Metal Salts ◽  
Transition Metal Salts
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