Viscosities and activation energies of viscous flow of the ternary mixtures of toluene, chlorobenzene, 1-hexanol, and benzyl alcohol

1985 ◽  
Vol 30 (4) ◽  
pp. 470-474 ◽  
Author(s):  
Ramesh P. Singh ◽  
Chandreshwar P. Sinha
Author(s):  
M. M. Holton ◽  
P. Gokulakrishnan ◽  
M. S. Klassen ◽  
R. J. Roby ◽  
G. S. Jackson

Autoignition delay experiments in air have been performed in an atmospheric flow reactor using typical natural gas components, namely, methane, ethane, and propane. Autoignition delay measurements were also made for binary fuel mixtures of methane/ethane and methane/propane, and ternary mixtures of methane/ethane/propane. The effect of CO2 addition to the methane-based fuel blends on autoignition delay times was also investigated. Equivalence ratios for the experiments ranged between 0.5 and 1.25, and temperatures ranged from 930 K to 1140 K. Consistent with past studies, increasing equivalence ratio and increasing inlet temperatures over these ranges decreased autoignition delay times. Furthermore, addition of 5–10% ethane or propane decreased autoignition delay time of the binary methane-based fuel by 30–50%. Further addition of either ethane or propane showed less significant reduction of autoignition delays. Addition of 5–10% CO2 slightly decreased the autoignition delay times of methane fuel mixtures. Arrhenius correlations were used to derive activation energies for the ignition of the pure fuels and their mixtures. Results show a reduction in activation energies at the higher temperatures studied, which suggests a change in ignition chemistry at very high temperatures. Measurements show relatively good agreement with predictions from a detailed kinetics mechanism, specifically developed to model ignition chemistry of C1-C3 alkanes.


1992 ◽  
Vol 65 (2) ◽  
pp. 503-511 ◽  
Author(s):  
Fulvio Corradini ◽  
Luigi Marcheselli ◽  
Andrea Marchetti ◽  
Mara Tagliazucchi ◽  
Lorenzo Tassi ◽  
...  

2019 ◽  
Vol 48 (5) ◽  
pp. 415-420
Author(s):  
Tian Fang ◽  
Daiyong Ye

Purpose This paper aims to prepare good waterborne light-diffusion dip-coatings (WLDDC) for the glass lampshade inner walls of LED lamp tubes, the effects of viscosities and viscous flow activation energies on these dip-coatings were investigated. Design/methodology/approach The WLDDC were prepared using white pigments, light-diffusion agents, additives and an acrylic emulsion. The dip-coatings were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy and a digital rotational viscometer, respectively. The effects of shear rates, temperatures and solids contents on the viscosities of the dip-coatings were studied. The viscous flow activation energies of these dip-coatings and the emulsion were calculated, compared and studied, respectively. Findings The results showed that the non-Newtonian behaviors of these dip-coatings were more prominent than that of the acrylic emulsion. When the temperature was maintained to be a constant and the shear rate was increased, the viscosity decreased and the shear stress increased. When the shear rate was maintained to be a constant, the viscosity decreased with increasing temperatures. The viscous flow activation energies of these dip-coatings decreased with the increasing shear rates. The higher solid contents of WLDDC were, the more its viscosity would decrease with the increasing shear rates, the more prominent its non-Newtonian behaviors would show. Practical implications A sample of good WLDDC with balanced properties was illustrated. Originality/value This investigation benefits to investigate waterborne environment-friendly dip-coatings for the inner glass walls of lamp tubes. This research provides an approach to optimize the viscosity parameters of light-diffusion dip-coatings.


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