Chiral (.eta.6-arene)chromium complexes in organic synthesis: stereoselective synthesis of chiral (arene)chromium complexes possessing amine and hydroxy groups and their application to asymmetric reactions

Motokazu Uemura; Ryuta Miyake; Kazuo Nakayama; Motoo Shiro; Yuji Hayashi

doi:10.1021/jo00057a042

Chiral (.eta.6-arene)chromium complexes in organic synthesis: stereoselective synthesis of chiral (arene)chromium complexes possessing amine and hydroxy groups and their application to asymmetric reactions

The Journal of Organic Chemistry ◽

10.1021/jo00057a042 ◽

1993 ◽

Vol 58 (5) ◽

pp. 1238-1244 ◽

Cited By ~ 72

Author(s):

Motokazu Uemura ◽

Ryuta Miyake ◽

Kazuo Nakayama ◽

Motoo Shiro ◽

Yuji Hayashi

Keyword(s):

Organic Synthesis ◽

Stereoselective Synthesis ◽

Asymmetric Reactions ◽

Chromium Complexes ◽

Hydroxy Groups

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ChemInform Abstract: Chiral (η6-Arene)chromium Complexes in Organic Synthesis: Stereoselective Synthesis of Chiral (Arene)chromium Complexes Possessing Amine and Hydroxy Groups and Their Application to Asymmetric Reactions.

ChemInform ◽

10.1002/chin.199324067 ◽

2010 ◽

Vol 24 (24) ◽

pp. no-no

Author(s):

M. UEMURA ◽

R. MIYAKE ◽

K. NAKAYAMA ◽

M. SHIRO ◽

Y. HAYASHI

Keyword(s):

Organic Synthesis ◽

Stereoselective Synthesis ◽

Asymmetric Reactions ◽

Chromium Complexes ◽

Hydroxy Groups

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Stereoselective synthesis of (η6-arene)chromium complexes possessing chiral amine and hydroxy groups: chiral ligands in asymmetric synthesis

Tetrahedron Letters ◽

10.1016/0040-4039(91)80041-4 ◽

1991 ◽

Vol 32 (35) ◽

pp. 4569-4572 ◽

Cited By ~ 21

Author(s):

Motokazu Uemura ◽

Ryuta Miyake ◽

Motoo Shiro ◽

Yuji Hayashi

Keyword(s):

Asymmetric Synthesis ◽

Stereoselective Synthesis ◽

Chiral Ligands ◽

Chromium Complexes ◽

Chiral Amine ◽

Hydroxy Groups

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Application of elementoorganic compounds of 15th and 16th Groups in organic synthesis. 100. Reactions of carbonyl compounds with [(trimethylsilyl)propargyl]diisobutyltelluronium bromide mediated by different strong bases: highly regioselective synthesis of (trimethylsilyl)propargyl alcohols and highly stereoselective synthesis of cis-(trimethylsilyl)alkynyl epoxides

The Journal of Organic Chemistry ◽

10.1021/jo00050a042 ◽

1992 ◽

Vol 57 (24) ◽

pp. 6598-6603 ◽

Cited By ~ 22

Author(s):

Zhanglin Zhou ◽

Yaozeng Huang ◽

Lilan Shi ◽

Jiong Hu

Keyword(s):

Organic Synthesis ◽

Carbonyl Compounds ◽

Stereoselective Synthesis ◽

Regioselective Synthesis ◽

Propargyl Alcohols

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ChemInform Abstract: New Methods and Reagents in Organic Synthesis. Part 65. A Stereoselective Synthesis of Tilivalline.

ChemInform ◽

10.1002/chin.198720337 ◽

1987 ◽

Vol 18 (20) ◽

Author(s):

S. MORI ◽

T. AOYAMA ◽

T. SHIOIRI

Keyword(s):

Organic Synthesis ◽

Stereoselective Synthesis ◽

New Methods

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ChemInform Abstract: Proton-Coupled Electron Transfer in Organic Synthesis: Novel Homolytic Bond Activations and Catalytic Asymmetric Reactions with Free Radicals

ChemInform ◽

10.1002/chin.201510314 ◽

2015 ◽

Vol 46 (10) ◽

pp. no-no

Author(s):

Hatice G. Yayla ◽

Robert R. Knowles

Keyword(s):

Electron Transfer ◽

Free Radicals ◽

Organic Synthesis ◽

Asymmetric Reactions ◽

Proton Coupled Electron Transfer ◽

Catalytic Asymmetric ◽

Bond Activations ◽

Catalytic Asymmetric Reactions

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Asymmetric reactions of α-ketoacid-derived hemiacetals: Stereoselective synthesis of α-hydroxy acids

Tetrahedron ◽

10.1016/s0040-4020(98)00914-4 ◽

1998 ◽

Vol 54 (48) ◽

pp. 14549-14564 ◽

Cited By ~ 16

Author(s):

Sunil V. Pansare ◽

R.Gnana Ravi

Keyword(s):

Stereoselective Synthesis ◽

Asymmetric Reactions ◽

Hydroxy Acids

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ChemInform Abstract: EFFECT OF METALS IONS IN ORGANIC SYNTHESIS. PART 19. SELECTIVE REGENERATION OF CARBONYL AND HYDROXY GROUPS BY COPPER(II) CHLORIDE-PROMOTED HYDROLYSIS OF TOSYLHYDRAZONES AND ACETATES

Chemischer Informationsdienst ◽

10.1002/chin.198410068 ◽

1984 ◽

Vol 15 (10) ◽

Author(s):

O. ATTANASI ◽

M. GROSSI ◽

F. SERRA-ZANETTI

Keyword(s):

Organic Synthesis ◽

Hydroxy Groups ◽

Hydrolysis Of ◽

Selective Regeneration

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ChemInform Abstract: (η6-Arene)chromium Complexes in Organic Synthesis: Synthesis of (.+ -.)-Dihydroxyserrulatic Acid.

ChemInform ◽

10.1002/chin.199143206 ◽

2010 ◽

Vol 22 (43) ◽

pp. no-no

Author(s):

M. UEMURA ◽

H. NISHIMURA ◽

T. MINAMI ◽

Y. HAYASHI

Keyword(s):

Organic Synthesis ◽

Chromium Complexes

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ChemInform Abstract: DITHIOCARBAMATES IN ORGANIC SYNTHESIS. VIII. SYNTHETIC UTILITY OF ALLYLIC THIOLCARBAMATES. STEREOSELECTIVE SYNTHESIS OF SIMPLE NATURAL PRODUCTS INCLUDING OPTICALLY ACTIVE MANICONE AND β-SINENSAL

Chemischer Informationsdienst ◽

10.1002/chin.198018324 ◽

1980 ◽

Vol 11 (18) ◽

Author(s):

T. MIMURA ◽

Y. KIMURA ◽

T. NAKAI

Keyword(s):

Natural Products ◽

Organic Synthesis ◽

Stereoselective Synthesis ◽

Optically Active ◽

Synthetic Utility

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Synergistic Catalysis for Stereodivergent Synthesis of trans- and cis-Skipped Dienes

Synlett ◽

10.1055/s-0040-1707190 ◽

2020 ◽

Vol 31 (18) ◽

pp. 1741-1746

Author(s):

Shenqqing Zhu ◽

Lingling Chu ◽

Fang Wang

Keyword(s):

Transition Metal ◽

Organic Synthesis ◽

Stereoselective Synthesis ◽

Triplet Energy ◽

Synergistic Catalysis ◽

The Cross ◽

Transition Metal Catalyzed ◽

Metal Catalyzed ◽

Vinyl Triflates

Catalytic, stereoselective synthesis of skipped dienes is an important topic in organic synthesis. Summarized here are the transition-metal-catalyzed stereoselective approaches and a new, photoinduced stereodivergent strategy reported by our group recently. Our strategy utilizes a synergistic photoredox/nickel protocol to enable the cross-electrophile coupling of allylic carbonates and vinyl triflates to construct 1,4-dienes, the stereoselectivity of which was tuned by the triplet energy (E T) photocatalysts employed, offering a convenient and stereodivergent solution to (E)- and (Z)-1,4-dienes from one set of substrates.

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