Oxidation of substituted benzyl alcohols by pyridinium fluorochromate: a kinetic study

1988 ◽  
Vol 53 (10) ◽  
pp. 2154-2159 ◽  
Author(s):  
Kalyan K. Banerji
Keyword(s):  
Kinetic Study ◽  
Benzyl Alcohols ◽  
Pyridinium Fluorochromate

A kinetic study of the acceleration effect of substituted benzyl alcohols on the cationic photopolymerization rate of epoxidized natural oils

Polymer ◽  
2005 ◽  
Vol 46 (5) ◽  
pp. 1535-1541 ◽  
Author(s):  
Ricardo Acosta Ortiz ◽  
Diana Prieto López ◽  
María de Lourdes Guillén Cisneros ◽  
Julio Cesar Rico Valverde ◽  
James V. Crivello
Keyword(s):  
Kinetic Study ◽  
Benzyl Alcohols ◽  
Natural Oils ◽  
Cationic Photopolymerization

Kinetics and Mechanism of the Oxidation of Benzyl Alcohol and Benzaldehyde by Aqueous Sodium Dichromate

1975 ◽  
Vol 53 (24) ◽  
pp. 3709-3713 ◽  
Author(s):  
Donald G. Lee ◽  
Udo A. Spitzer
Keyword(s):  
Reaction Mechanism ◽  
Kinetic Study ◽  
Benzyl Alcohol ◽  
Oxidation Rate ◽  
Activation Parameters ◽  
Sodium Dichromate ◽  
Benzyl Alcohols ◽  
Aqueous Sodium ◽  
Entropy Of Activation ◽  
The Difference

A kinetic study of the oxidation of a series of substituted benzyl alcohols and benzaldehydes by neutral aqueous sodium dichromate has been completed. The aldehydes are more resistant to oxidation because the reaction mechanism presumably involves hydration prior to oxidation, and under the conditions employed the extent of this hydration is suppressed. These conclusions are consistent with the activation parameters which indicate that the difference in oxidation rate is due to a more negative entropy of activation for the aldehydes.

Kinetic study of the oxidation of thioacids by pyridinium fluorochromate

1991 ◽  
Vol 16 (6) ◽  
pp. 641-644 ◽  
Author(s):  
Kakuli Chowdhury ◽  
Sarswati Agarwal ◽  
Kalyan K. Banerji
Keyword(s):  
Kinetic Study ◽  
Pyridinium Fluorochromate

scholarly journals Kinetic Study on Induced Electron Transfer Reaction in Pentaamminecobalt(III) Complexes of α-Hydroxy Acids by Pyridinium Fluorochromate in Micellar Medium

2011 ◽  
Vol 8 (3) ◽  
pp. 1102-1107
Author(s):  
B. Mohammed Nawaz ◽  
K. Subramani ◽  
Mansur Ahmed
Keyword(s):  
Electron Transfer ◽  
Kinetic Study ◽  
Carbonyl Compounds ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Micellar Medium ◽  
Hydroxy Acids ◽  
Uv Visible ◽  
Pyridinium Fluorochromate

Pyridinium fluorochromate (PFC) oxidation of pentaamminecobalt(III) complexes of α-hydroxy acids in micellar medium yielding nearly 100% of carbonyl compounds are ultimate products. The decrease in UV-visible absorbance at λ=502 nm for Co(III) complex corresponds to nearly 100% of the initial absorbance. The stoichiometry of unbound ligand and cobalt(III) complex is accounting for about 100% reduction at the cobalt(III) centre. The kinetic and stoichiometric results have been accounted by a suitable mechanism.

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