Kinetic Study of the PhthalimideN-Oxyl Radical in Acetic Acid. Hydrogen Abstraction from Substituted Toluenes, Benzaldehydes, and Benzyl Alcohols

2003 ◽  
Vol 68 (24) ◽  
pp. 9364-9370 ◽  
Author(s):  
Nobuyoshi Koshino ◽  
Basudeb Saha ◽  
James H. Espenson
Keyword(s):  
Acetic Acid ◽  
Kinetic Study ◽  
Hydrogen Abstraction ◽  
Benzyl Alcohols ◽  
Substituted Toluenes

scholarly journals Synthesis of Nano-Sized Protonic Acid Catalyst and Initial Kinetic Study of Esterification Reaction of Methanol with Acetic Acid

2014 ◽  
Vol 26 (16) ◽  
pp. 4988-4994
Author(s):  
Jianjun Zhu ◽  
Qiuqing Cui ◽  
Jiangping Peng ◽  
Li Li Zhang ◽  
Zhongqing Jiang ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Kinetic Study ◽  
Acid Catalyst ◽  
Esterification Reaction ◽  
Protonic Acid

Aromatic oxidation by cobaltic acetate in acetic acid

1969 ◽  
Vol 47 (3) ◽  
pp. 387-392 ◽  
Author(s):  
Koichiro Sakota ◽  
Yoshio Kamiya ◽  
Nobuto Ohta
Keyword(s):  
Activation Energy ◽  
Electron Transfer ◽  
Acetic Acid ◽  
Bond Energy ◽  
Hydrogen Abstraction ◽  
Steric Factor ◽  
Benzyl Acetate ◽  
Kcal Mole ◽  
First Order ◽  
Reversible Electron Transfer

A detailed kinetic study of oxidation of toluene and its derivatives by cobaltic acetate in 95 vol% acetic acid is reported. The reaction was found to be profoundly affected by a steric factor and rather insensitive to the C—H bond energy. The order of reactivities of various alkylbenzenes is quite reversal to that of hydrogen abstraction reactions. The reaction was of first-order with respect to toluene, of second-order with respect to cobaltic ion and of inverse first-order with respect to cobaltous ion. The oxidation by cobaltic ion seems to proceed via an initial reversible electron transfer from toluene to cobaltic ion, yielding [Formula: see text] which is oxidized into benzyl acetate by another cobaltic ion. The apparent activation energy for toluene was found to be 25.3 kcal mole−1, and the same activation energy was found for ethylbenzene, cumene, diphenylmethane, and triphenylmethane.

Catalytic Behavior of Co-Based Catalysts in the Kinetic Study of Acetic Acid Steam Reforming

2020 ◽  
Vol 59 (44) ◽  
pp. 19531-19538
Author(s):  
Pedro J. Megía ◽  
Marta Cortese ◽  
Concetta Ruocco ◽  
Arturo J. Vizcaíno ◽  
José A. Calles ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Kinetic Study ◽  
Steam Reforming ◽  
Catalytic Behavior
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