Rate enhancement of nucleophilic substitution reactions in phosphate esters. Influence of conformational transmission on the rate of solvolysis in alkyl diphenylphosphinates

1989 ◽  
Vol 54 (6) ◽  
pp. 1453-1456 ◽  
Author(s):  
A. E. H. De Keijzer ◽  
L. H. Koole ◽  
W. J. M. Van der Hofstad ◽  
H. M. Buck
2021 ◽  
Vol 50 (7) ◽  
pp. 2671-2688
Author(s):  
Marina Yu. Stogniy ◽  
Sergey A. Anufriev ◽  
Akim V. Shmal'ko ◽  
Sergey M. Antropov ◽  
Aleksei A. Anisimov ◽  
...  

An unusual reactivity of 9-iodo-nido-carborane [9-I-7,8-C2B9H11]− towards nucleophiles under strong basic conditions was revealed.


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