One-Step Synthesis of Oxodimethylenemethane−Transition Metal Complexes and Palladium-Catalyzed Cycloaddition Reaction

1996 ◽  
Vol 61 (15) ◽  
pp. 4971-4974 ◽  
Author(s):  
Isao Ikeda ◽  
Akihiro Ohsuka ◽  
Kazuyoshi Tani ◽  
Toshikazu Hirao ◽  
Hideo Kurosawa
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Cycloaddition Reaction ◽  
Palladium Catalyzed ◽  
One Step

Straightforward synthesis and catalytic applications of rigid N,O-type calixarene ligands

2015 ◽  
Vol 13 (46) ◽  
pp. 11189-11193 ◽  
Author(s):  
Varun Rawat ◽  
Konstantin Press ◽  
Israel Goldberg ◽  
Arkadi Vigalok
Keyword(s):  
Catalytic Activity ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Main Group ◽  
Late Transition Metal ◽  
Organic Transformations ◽  
One Step ◽  
Catalytic Applications ◽  
Late Transition

Here, we report a simple one-step access to new rigid N,O-calixarene ligands which is based on copper-catalized amination at the lower rim. We also present their main group and late transition metal complexes which show superior catalytic activity, in several organic transformations, compared with known metal calixarene complexes.

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