Nonideality in Binary Mixtures: Correlations between Excess Volume, Excess Viscosity, and Diffusion Coefficients

2001 ◽  
Vol 105 (39) ◽  
pp. 9581-9585 ◽  
Author(s):  
Arnab Mukherjee ◽  
Biman Bagchi
Keyword(s):  
Binary Mixtures ◽  
Diffusion Coefficients ◽  
Excess Volume ◽  
Excess Viscosity ◽  
And Diffusion

Calculation of viscosity and diffusion coefficients in binary mixtures of dilute gases

2017 ◽  
Vol 11 ◽  
pp. 283-296
Author(s):  
A. F. Bogatyrev ◽  
O. A. Makeenkova ◽  
V. R. Belalov ◽  
M. A. Kucherenko
Keyword(s):  
Binary Mixtures ◽  
Diffusion Coefficients ◽  
Dilute Gases ◽  
And Diffusion

Viscosity and density of isomeric butanol/water mixtures as functions of composition and temperature

1987 ◽  
Vol 65 (10) ◽  
pp. 2441-2446 ◽  
Author(s):  
P. Chandani Senanayake ◽  
Norman Gee ◽  
Gordon R. Freeman
Keyword(s):  
Binary Mixtures ◽  
Mole Fraction ◽  
Excess Volume ◽  
Excess Viscosity ◽  
Tert Butanol

Viscosity and density of 27 binary mixtures of sec-, iso-, and tert-butanol with water were measured at 273 ≤ T/K ≤ 353 and the results summarized using polynomials. At fixed T the density depended strongly but monotonically on mole fraction. The excess volume VE was large and negative. In H2O/tert-butanol as T increased VE increased, while in H2O/sec- or iso-butanol VE decreased with increasing T. The excess viscosity was large and positive in all cases.

PREDICTION OF THE TRANSPORT PROPERTIES OF SF6 WITH O2, CO2, CF4, N2 AND CH4 MIXTURES AT LOW DENSITY BY THE INVERSION METHOD (PART II)

2004 ◽  
Vol 03 (01) ◽  
pp. 69-90 ◽  
Author(s):  
BEHZAD HAGHIGHI ◽  
ALIREZA HASSANI DJAVANMARDI ◽  
MOHAMAD MEHDI PAPARI ◽  
MOHSEN NAJAFI
Keyword(s):  
Potential Energy ◽  
Diffusion Coefficients ◽  
Potential Energy Function ◽  
Model Potential ◽  
Inversion Method ◽  
Low Density ◽  
Initial Model ◽  
Lennard Jones ◽  
Inversion Procedure ◽  
And Diffusion

Viscosity and diffusion coefficients for five equimolar binary gas mixtures of SF 6 with O 2, CO 2, CF 4, N 2 and CH 4 gases are determined from the extended principle of corresponding states of viscosity by the inversion technique. The Lennard–Jones 12-6 (LJ 12-6) potential energy function is used as the initial model potential required by the technique. The obtained interaction potential energies from the inversion procedure reproduce viscosity within 1% and diffusion coefficients within 5%.

scholarly journals Boundary behavior and product-form stationary distributions of jump diffusions in the orthant with state-dependent reflections

2008 ◽  
Vol 40 (02) ◽  
pp. 529-547
Author(s):  
Francisco J. Piera ◽  
Ravi R. Mazumdar ◽  
Fabrice M. Guillemin
Keyword(s):  
Random Fields ◽  
Diffusion Coefficients ◽  
Boundary Behavior ◽  
Stationary Regime ◽  
Product Form ◽  
Local Times ◽  
Nonnegative Orthant ◽  
State Dependent ◽  
The Times ◽  
And Diffusion

In this paper we consider reflected diffusions with positive and negative jumps, constrained to lie in the nonnegative orthant of ℝ n . We allow for the drift and diffusion coefficients, as well as for the directions of reflection, to be random fields over time and space. We provide a boundary behavior characterization, generalizing known results in the nonrandom coefficients and constant directions of the reflection case. In particular, the regulator processes are related to semimartingale local times at the boundaries, and they are shown not to charge the times the process expends at the intersection of boundary faces. Using the boundary results, we extend the conditions for product-form distributions in the stationary regime to the case when the drift and diffusion coefficients, as well as the directions of reflection, are random fields over space.

scholarly journals The rate of evaporation of droplets. Evaporation and diffusion coefficients, and vapour pressures of dibutyl phthalate and butyl stearate

1946 ◽  
Vol 186 (1006) ◽  
pp. 368-390 ◽  
Keyword(s):  
Diffusion Coefficients ◽  
Atmospheric Pressure ◽  
Dibutyl Phthalate ◽  
Droplet Evaporation ◽  
Medium Size ◽  
Good Accordance ◽  
Butyl Stearate ◽  
Rate Of Evaporation ◽  
Low Pressures ◽  
And Diffusion

The rate of evaporation of drops of dibutyl phthalate and butyl stearate of radius approx. 0.5 mm. has been studied by means of a microbalance over a range of atmospheric pressures down to approx. 0*1 mm. of mercury. Wide departures from Langmuir’s evaporation formula were found to occur at these low pressures, but results are in good accordance with the theory of droplet evaporation advanced by Fuchs which hitherto has not been tested experimentally. This experimental verification of Fuch’s theory for droplets of medium size evaporating at low pressures shows that the theory can be applied to the evaporation of very small drops at atmospheric pressure. The vapour pressures of the above liquids have been measured by Knudsen’s method and the evaporation and diffusion coefficients calculated fro n the experimental data.

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