Chemical Diffusion Coefficient of Electrons in Nanostructured Semiconductor Electrodes and Dye-Sensitized Solar Cells

2004 ◽  
Vol 108 (7) ◽  
pp. 2323-2332 ◽  
Author(s):  
Juan Bisquert



2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
En Mei Jin ◽  
Kyung-Hee Park ◽  
Ju-Young Park ◽  
Jae-Wook Lee ◽  
Soon-Ho Yim ◽  
...  

A chitosan binder-based TiO2photoelectrode is used in dye-sensitized solar cells (DSSCs). Field-emission scanning electron microscope (FE-SEM) images revealed that the grain size, thickness, and distribution of TiO2films are affected by the chitosan content. With addition of 2.0 wt% chitosan to the TiO2film (D2), the surface pore size became the smallest, and the pores were fairly evenly distributed. The electron transit time, electron recombination lifetime, diffusion coefficient, and diffusion length were analyzed by IMVS and IMPS. The best DSSC, with 2.0 wt% chitosan addition to the TiO2film, had a shorter electron transit time, longer electron recombination lifetime, and larger diffusion coefficient and diffusion length than the other samples. The results of 2.0 wt% chitosan-added TiO2DSSCs are an electron transit time of  s, electron recombination lifetime of  s, diffusion coefficient of  cm2s−1, diffusion length of 14.81 μm, and a solar conversion efficiency of 4.18%.



2010 ◽  
Vol 115 (1) ◽  
pp. 120-131 ◽  
Author(s):  
K. Tennakone ◽  
G. L. M. P. Apsonsu ◽  
Y. P. Y. P. Ariyasinghe ◽  
R. C. Buchanan ◽  
V. P. S. Perera ◽  
...  


2017 ◽  
Vol 2017 ◽  
pp. 1-31 ◽  
Author(s):  
Carmen Cavallo ◽  
Francesco Di Pascasio ◽  
Alessandro Latini ◽  
Matteo Bonomo ◽  
Danilo Dini

Since O’Regan and Grätzel’s first report in 1991, dye-sensitized solar cells (DSSCs) appeared immediately as a promising low-cost photovoltaic technology. In fact, though being far less efficient than conventional silicon-based photovoltaics (being the maximum, lab scale prototype reported efficiency around 13%), the simple design of the device and the absence of the strict and expensive manufacturing processes needed for conventional photovoltaics make them attractive in small-power applications especially in low-light conditions, where they outperform their silicon counterparts. Nanomaterials are at the very heart of DSSC, as the success of its design is due to the use of nanostructures at both the anode and the cathode. In this review, we present the state of the art for bothn-type andp-type semiconductors used in the photoelectrodes of DSSCs, showing the evolution of the materials during the 25 years of history of this kind of devices. In the case ofp-type semiconductors, also some other energy conversion applications are touched upon.



2010 ◽  
Vol 451 ◽  
pp. 97-121 ◽  
Author(s):  
James R. Jennings ◽  
Qing Wang

General characteristics of dye-sensitized nanoporous semiconductor electrode systems are summarized, with a particular emphasis on dye-sensitized solar cells. Properties of these electrode systems which distinguish them from conventional bulk semiconductor electrodes are highlighted. Current understanding of electron transport in dye-sensitized solar cells, in terms of the diffusion and multiple trapping models, is reviewed. Alternative transport and recombination theories are also briefly reviewed. Electron transfer at the semiconductor/electrolyte interface in dye-sensitized solar cells is reviewed and recent experimental results obtained by the authors are highlighted. As applicable, common techniques for characterization of electron transport and transfer in dye-sensitized solar cells are described, with reference to case studies where the electron diffusion length in dye-sensitized solar cells has been estimated. The steady-state aspects of the dye-regeneration process are also reviewed, together with the cross-surface percolation of holes in the dye monolayer and the finite-length diffusion of redox species in the electrolyte.







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