Radiation Induced Redox Reactions and Fragmentation of Constituent Ions in Ionic Liquids. 2. Imidazolium Cations

2011 ◽  
Vol 115 (14) ◽  
pp. 3889-3902 ◽  
Author(s):  
Ilya A. Shkrob ◽  
Timothy W. Marin ◽  
Sergey D. Chemerisov ◽  
Jasmine L. Hatcher ◽  
James F. Wishart
Keyword(s):  
Ionic Liquids ◽  
Redox Reactions ◽  
Imidazolium Cations ◽  
Radiation Induced

Radiation Induced Redox Reactions and Fragmentation of Constituent Ions in Ionic Liquids. 1. Anions

2011 ◽  
Vol 115 (14) ◽  
pp. 3872-3888 ◽  
Author(s):  
Ilya A. Shkrob ◽  
Timothy W. Marin ◽  
Sergey D. Chemerisov ◽  
James F. Wishart
Keyword(s):  
Ionic Liquids ◽  
Redox Reactions ◽  
Radiation Induced

15N NMR spectra of some ionic liquids based on 1,3-disubstituted imidazolium cations

2006 ◽  
Vol 44 (5) ◽  
pp. 521-523 ◽  
Author(s):  
Antonín Lyčka ◽  
Roman Doleček ◽  
Petr Šimûnek ◽  
Vladimír Macháček
Keyword(s):  
Ionic Liquids ◽  
Nmr Spectra ◽  
15N Nmr ◽  
Imidazolium Cations

scholarly journals Study of γ Radiation-Induced Colored Products on [Cnmim][NTf2] Ionic Liquids

2013 ◽  
Vol 29 (03) ◽  
pp. 619-624 ◽  
Author(s):  
CUI Zhen-Peng ◽  
◽  
WANG Shuo-Jue ◽  
AO Yin-Yong ◽  
PENG Jing ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Gamma Radiation ◽  
Radiation Induced

scholarly journals Introduction of Bifunctional Group onto MWNT by Radiation-Induced Graft Polymerization and Its Use as Biosensor-Supporting Materials

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
Yu-Jin Lee ◽  
Da-Jung Chung ◽  
Sang-Hyub Oh ◽  
Seong-Ho Choi
Keyword(s):  
Photoelectron Spectroscopy ◽  
Glycidyl Methacrylate ◽  
Redox Reactions ◽  
Graft Polymerization ◽  
Red Wine ◽  
Multiwalled Carbon ◽  
X Ray ◽  
Transmission Electron ◽  
Radiation Induced ◽  
Supporting Materials

A biosensor comprisingtyrosinaseimmobilized on bifunctionalized multiwalled carbon nanotube (MWNT) supports was prepared for the detection of phenolic compounds in drinks such as red wine and juices. The MWNT supports were prepared by radiation-induced graft polymerization (RIGP) of epoxy-containing glycidyl methacrylate (GMA), to covalently immobilize thetyrosinase, and vinyl ferrocene (VF), which can act as an electron transfer mediator via redox reactions. The bifunctionalized MWNTs were characterized by X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and thermogravimetric analysis (TGA). Electrodes prepared with the MWNTs showed increased current with increasing VF content. A biosensor comprisingtyrosinaseimmobilized on the bifunctionalized MWNTs could detect phenol at 0.1–20 mM. Phenolics in red wine and juices were determined using the biosensor after its calibration.

scholarly journals Optical properties of irradiated imidazolium based room temperature ionic liquids: new microscopic insights into the radiation induced mutations

2015 ◽  
Vol 17 (16) ◽  
pp. 11053-11061 ◽  
Author(s):  
Apurav Guleria ◽  
Ajay K Singh ◽  
Soumyakanti Adhikari
Keyword(s):  
Optical Properties ◽  
Electron Beam ◽  
Ionic Liquids ◽  
Room Temperature ◽  
Room Temperature Ionic Liquids ◽  
Induced Mutations ◽  
Molecular Rearrangements ◽  
Radiation Induced

The optical properties of electron beam irradiated RTILs revealed significant changes in the molecular rearrangements and realignment of bonding interactions. This study could be useful for comprehensively understanding the radiation driven effects in the ILs.

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