Chiral Recognition of Amino Acid Enantiomers by a Crown Ether: Chiroptical IR-VCD Response and Computational Study

2013 ◽  
Vol 117 (32) ◽  
pp. 9362-9370 ◽  
Author(s):  
Juan Ramón Avilés-Moreno ◽  
María Mar Quesada-Moreno ◽  
Juan Jesús López-González ◽  
Bruno Martínez-Haya
2016 ◽  
Vol 40 (4) ◽  
pp. 3194-3207 ◽  
Author(s):  
Ya-Ya Song ◽  
Xiao-Dong Song ◽  
Heng Yuan ◽  
Chang-Jing Cheng

A novel type of multifunctional magnetic nanoparticle with highly chiral recognition capability, excellent thermo-sensitive adsorption and decomplexation properties toward amino acid enantiomers, and recyclability was developed in this study.


2001 ◽  
Vol 910 (2) ◽  
pp. 359-365 ◽  
Author(s):  
Myung Ho Hyun ◽  
Sang Cheol Han ◽  
Bruce H. Lipshutz ◽  
Young-Jun Shin ◽  
Christopher J. Welch

2016 ◽  
Vol 70 (10) ◽  
pp. 1649-1654 ◽  
Author(s):  
Lu Huang ◽  
Yi-Ting Chen ◽  
Yan-Xia Li ◽  
Li-Shuang Yu

Two chiral ionic liquids (ILs), namely 1-ethyl-3-methylimidazole l-tartrate (EMIML-Tar) and 1-ethyl-3-methylimidazole l-lactate (EMIML-Lac), were used to modify gold nanoparticles (AuNPs) for chiral recognition of amino acid enantiomers. Transmission electron microscopy, infrared spectroscopy, ultraviolet-visible spectroscopy, and capillary electrophoresis were used for the characterization of chiral IL-modified AuNPs. Meanwhile, the performance of l-tartaric acid and l-lactic acid as modifiers was investigated to make a comparison. The chiral recognition mechanism is further discussed.


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