Thermo-responsive adsorption and separation of amino acid enantiomers using smart polymer-brush-modified magnetic nanoparticles

2016 ◽  
Vol 40 (4) ◽  
pp. 3194-3207 ◽  
Author(s):  
Ya-Ya Song ◽  
Xiao-Dong Song ◽  
Heng Yuan ◽  
Chang-Jing Cheng

A novel type of multifunctional magnetic nanoparticle with highly chiral recognition capability, excellent thermo-sensitive adsorption and decomplexation properties toward amino acid enantiomers, and recyclability was developed in this study.

Langmuir ◽  
2011 ◽  
Vol 27 (6) ◽  
pp. 3106-3112 ◽  
Author(s):  
Fei Xu ◽  
James H. Geiger ◽  
Gregory L. Baker ◽  
Merlin L. Bruening

2018 ◽  
Vol 5 (6) ◽  
pp. 065014
Author(s):  
Yufan Gu ◽  
Shuxin Deng ◽  
Ting Su ◽  
Gancheng Zuo ◽  
Xihao Pan ◽  
...  

2014 ◽  
Vol 50 ◽  
pp. 124-134 ◽  
Author(s):  
Yinjia Jin ◽  
Fei Liu ◽  
Chao Shan ◽  
Meiping Tong ◽  
Yanglong Hou

2013 ◽  
Vol 117 (32) ◽  
pp. 9362-9370 ◽  
Author(s):  
Juan Ramón Avilés-Moreno ◽  
María Mar Quesada-Moreno ◽  
Juan Jesús López-González ◽  
Bruno Martínez-Haya

2008 ◽  
Vol 8 (8) ◽  
pp. 4033-4040 ◽  
Author(s):  
John E. Wong ◽  
Akhilesh K. Gaharwar ◽  
Detlef Müller-Schulte ◽  
Dhirendra Bahadur ◽  
Walter Richtering

This study describes the surface modification of magnetic nanoparticles using two different approaches. The first approach consists of an in situ modification of the surface during the precipitation of the magnetic nanoparticles while the second approach consists of a post-modification of the surface after the formation of the magnetic nanoparticles. In the latter case, we adopted the Layer-by-Layer assembly of polyelectrolyte multilayers of poly(diallyl-dimethylammonium) chloride and poly(styrenesulfonate) to build a polymeric shell around the magnetic nanoparticle core, thereby intentionally conferring to this hybrid core–shell the same charge as the charge of the polyelectrolyte deposited in the last layer. Electrophoretic measurements reveal charge reversal indicating successful Layer-by-Layer deposition while magnetization studies show that the superparamagnetic behavior is not much affected by the presence of polyelectrolytes on the modified magnetic nanoparticles. Fourier transform infrared and thermogravimetry analysis results underline that the various polyelectrolytes employed, in both the methodologies adopted, were successfully bound to the nanoparticles.


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