Oxygen Atom Transfer Reactions from Mimoun Complexes to Sulfides and Sulfoxides. A Bonding Evolution Theory Analysis

2014 ◽  
Vol 118 (31) ◽  
pp. 6092-6103 ◽  
Author(s):  
Patricio González-Navarrete ◽  
Fabricio R. Sensato ◽  
Juan Andrés ◽  
Elson Longo
Keyword(s):  
Oxygen Atom ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Evolution Theory ◽  
Oxygen Atom Transfer ◽  
Theory Analysis ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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