Superlubricity Behavior with Phosphoric Acid–Water Network Induced by Rubbing

Langmuir ◽  
2011 ◽  
Vol 27 (15) ◽  
pp. 9413-9417 ◽  
Author(s):  
Jinjin Li ◽  
Chenhui Zhang ◽  
Jianbin Luo

1991 ◽  
Vol 24 (5) ◽  
pp. 1161-1167 ◽  
Author(s):  
Yachin Cohen ◽  
Yasuo Saruyama ◽  
Edwin L. Thomas








1984 ◽  
Vol 23 (13) ◽  
pp. 1922-1926 ◽  
Author(s):  
R. M. H. Verbeeck ◽  
P. A. M. De Bruyne ◽  
F. C. M. Driessens ◽  
F. Verbeek


1981 ◽  
Vol 26 (3) ◽  
pp. 295-300 ◽  
Author(s):  
Yong K. Kim ◽  
Henry K. Walters ◽  
John D. Hatfield


1988 ◽  
Vol 33 (4) ◽  
pp. 518-523 ◽  
Author(s):  
A. William Frazier ◽  
Kjell R. Waerstad ◽  
Yong K. Kim


2007 ◽  
Vol 85 (5) ◽  
pp. 346-351 ◽  
Author(s):  
Kenneth E Newman ◽  
Raymond E Ortlieb ◽  
Nicole Pawlik ◽  
Jason Reedyk

When dissolved in concentrated phosphoric acid, sodium fluoride reacts rapidly to form monofluorophosphate. In less concentrated acid, the reaction does not proceed to completion, and the reaction kinetics become very much slower. The equilibrium and rate constants for the reaction have been determined. In ternary mixtures of phosphoric acid, sulfuric acid, and water, the formation of monofluorophosphate is considerably enhanced, and the kinetics are rapid. The results are interpreted in terms of the very low water activity coefficients in strong-acid solutions.Key words: monofluorophosphate, monofluorophosphoric acid, 19F NMR, 31P NMR, phosphoric acid, sulufric acid, equilibria, kinetics.



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