scholarly journals Correlating Particle Deformation with Water Concentration Profiles during Latex Film Formation: Reasons That Softer Latex Films Take Longer to Dry

Langmuir ◽  
2014 ◽  
Vol 30 (32) ◽  
pp. 9672-9681 ◽  
Author(s):  
Farai T. Carter ◽  
Radoslaw M. Kowalczyk ◽  
Ian Millichamp ◽  
Malcolm Chainey ◽  
Joseph L. Keddie
Keyword(s):  
Film Formation ◽  
Water Concentration ◽  
Latex Film ◽  
Concentration Profiles ◽  
Particle Deformation ◽  
Latex Films ◽  
Latex Film Formation

Role of Water in Particle Deformation and Compaction in Latex Film Formation

Langmuir ◽  
1994 ◽  
Vol 10 (8) ◽  
pp. 2619-2628 ◽  
Author(s):  
P. R. Sperry ◽  
B. S. Snyder ◽  
M. L. O'Dowd ◽  
P. M. Lesko
Keyword(s):  
Film Formation ◽  
Latex Film ◽  
Particle Deformation ◽  
Latex Film Formation

Interactions between aroma compounds and latex films: partition coefficients and influence on latex film formation

2006 ◽  
Vol 19 (2) ◽  
pp. 71-82 ◽  
Author(s):  
A. Nestorson ◽  
A. Leufvén ◽  
L. Järnström
Keyword(s):  
Partition Coefficients ◽  
Film Formation ◽  
Aroma Compounds ◽  
Latex Film ◽  
Latex Films ◽  
Latex Film Formation

scholarly journals Tracking Hydroplasticization by DSC: Movement of Water Domains Bound to Poly(Meth)Acrylates during Latex Film Formation

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2500
Author(s):  
Sebastian M. Dron ◽  
Maria Paulis
Keyword(s):  
Itaconic Acid ◽  
Water Resistance ◽  
Film Formation ◽  
Latex Film ◽  
Water Molecules ◽  
Acrylate Copolymer ◽  
Volatile Organic ◽  
Minimum Film Formation Temperature ◽  
Latex Film Formation ◽  
Formation Step

The film formation step of latexes constitutes one of the challenges of these environmentally friendly waterborne polymers, as the high glass transition (TG) polymers needed to produce hard films to be used as coatings will not produce coherent films at low temperature. This issue has been dealt by the use of temporary plasticizers added with the objective to reduce the TG of the polymers during film formation, while being released to the atmosphere afterwards. The main problem of these temporary plasticizers is their volatile organic nature, which is not recommended for the environment. Therefore, different strategies have been proposed to overcome their massive use. One of them is the use of hydroplasticization, as water, abundant in latexes, can effectively act as plasticizer for certain types of polymers. In this work, the effect of three different grafted hydroplasticizers has been checked in a (meth)acrylate copolymer, concluding that itaconic acid showed the best performance as seen by its low minimum film-formation temperature, just slightly modified water resistance and better mechanical properties of the films containing itaconic acid. Furthermore, film formation monitoring has been carried out by Differential Scanning Calorimety (DSC), showing that itaconic acid is able to retain more strongly the water molecules during the water losing process, improving its hydroplasticization capacity.

An overview of polymer latex film formation and properties

2000 ◽  
Vol 86 (3) ◽  
pp. 195-267 ◽  
Author(s):  
P.A. Steward ◽  
J. Hearn ◽  
M.C. Wilkinson
Keyword(s):  
Film Formation ◽  
Latex Film ◽  
Latex Film Formation ◽  
Polymer Latex

Acrylic latex film formation in the critical temperature range

1964 ◽  
Vol 8 (2) ◽  
pp. 755-764 ◽  
Author(s):  
Raymond R. Myers ◽  
Ray K. Schultz
Keyword(s):  
Critical Temperature ◽  
Film Formation ◽  
Latex Film ◽  
Temperature Range ◽  
Acrylic Latex ◽  
Latex Film Formation

Simulation of interdiffusion and its monitoring by direct energy transfer during latex film formation

Polymer ◽  
1998 ◽  
Vol 39 (10) ◽  
pp. 1983-1989 ◽  
Author(s):  
K.S. Güntürk ◽  
A.T. Giz ◽  
Ö. Pekcan
Keyword(s):  
Energy Transfer ◽  
Film Formation ◽  
Latex Film ◽  
Direct Energy ◽  
Latex Film Formation ◽  
Direct Energy Transfer

Effect of Molecular Weight on Packing during Latex Film Formation

2001 ◽  
Vol 234 (1) ◽  
pp. 72-78 ◽  
Author(s):  
Ertan Arda ◽  
Önder Pekcan
Keyword(s):  
Molecular Weight ◽  
Film Formation ◽  
Latex Film ◽  
Latex Film Formation

Deformation Mechanisms during Latex Film Formation:  Experimental Evidence

2001 ◽  
Vol 40 (20) ◽  
pp. 4302-4308 ◽  
Author(s):  
Alexander F. Routh ◽  
William B. Russel
Keyword(s):  
Experimental Evidence ◽  
Film Formation ◽  
Deformation Mechanisms ◽  
Latex Film ◽  
Latex Film Formation

Molecular diffusion and latex film formation: An analysis of direct nonradiative energy transfer experiments

1991 ◽  
Vol 95 (3) ◽  
pp. 2143-2153 ◽  
Author(s):  
Yongcai Wang ◽  
Cheng‐Le Zhao ◽  
Mitchell A. Winnik
Keyword(s):  
Energy Transfer ◽  
Molecular Diffusion ◽  
Film Formation ◽  
Nonradiative Energy Transfer ◽  
Latex Film ◽  
Latex Film Formation
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