Solution properties of ultrahigh molecular weight polymers. 5. Conformational changes of butyl methacrylate-styrene copolymers in dilute solution

1985 ◽  
Vol 18 (10) ◽  
pp. 1995-1999 ◽  
Author(s):  
Cristofor I. Simionescu ◽  
Bogdan C. Simionescu ◽  
Silvia Ioan

1992 ◽  
Vol 27 (5) ◽  
pp. 571-575 ◽  
Author(s):  
Maria Bercea ◽  
Silvia Ioan ◽  
Bogdan C. Simionescu ◽  
Cristofor I. Simionescu


1985 ◽  
Vol 23 (3) ◽  
pp. 121-127 ◽  
Author(s):  
Cristofor I. Simionescu ◽  
Bogdan C. Simionescu ◽  
Silvia Ioan








1992 ◽  
Vol 65 (2) ◽  
pp. 303-314 ◽  
Author(s):  
L-L. Zhou ◽  
N. Hadjichristidis ◽  
P. M. Toporowski ◽  
J. Roovers

Abstract A dendrimer carbosilane containing 32 Si—Cl bonds in the perimeter has been prepared and has been used as a coupling agent to prepare 32-arm star polybutadienes. The dilute-solution properties 〈RG2〉, A2, [η], and D0 have been measured in one good solvent and in one ¸ -solvent. The dimensions of the 32-arm star polymers are compared with those of linear polymers at constant molecular weight. It is shown that the 32-arm star polybutadiene has the characteristic properties of a hard-sphere molecule in dilute solution. The equivalent hard-sphere radii calculated from A2, D0 and [η] are identical and 1.29 times larger than the root mean-square radius of gyration. The Daoud—Cotton scaling model for stars is also tested.





1998 ◽  
Vol 37 (3) ◽  
pp. 285-294 ◽  
Author(s):  
Maria Bercea ◽  
Câtâlina Ioan ◽  
Simona Morariu ◽  
Silvia Ioan ◽  
Bogdan C. Simionescud


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