Hydrogenation and Redox Isomerization of Allylic Alcohols Catalyzed by a New Water-Soluble Pd–tetrahydrosalen Complex

2013 ◽  
Vol 32 (15) ◽  
pp. 4391-4401 ◽  
Author(s):  
Krisztina Voronova ◽  
Mihály Purgel ◽  
Antal Udvardy ◽  
Attila C. Bényei ◽  
Ágnes Kathó ◽  
...  
Keyword(s):  
Water Soluble ◽  
Allylic Alcohols ◽  
Redox Isomerization

scholarly journals Redox Isomerization of Allylic Alcohols Catalyzed by New Water-Soluble Rh(I)-N-Heterocyclic Carbene Complexes

Catalysts ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1361
Author(s):  
Csilla Enikő Czégéni ◽  
Marianna Fekete ◽  
Eszter Tóbiás ◽  
Antal Udvardy ◽  
Henrietta Horváth ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Aqueous Phase ◽  
Aqueous Media ◽  
Water Soluble ◽  
Allylic Alcohols ◽  
Tertiary Phosphine ◽  
Carbene Complexes ◽  
Phosphine Complexes ◽  
First Time ◽  
Redox Isomerization

New water-soluble, N-heterocyclic carbene (NHC) or mixed NHC/tertiary phosphine complexes [RhCl(cod)(sSIMes)], Na2[Rh(bmim)(cod)(mtppts)], and [Rh(bmim)(cod)(pta)]BF4 were synthetized and applied for the first time as catalysts in redox isomerization of allylic alcohols in aqueous media. [RhCl(cod)(sSIMes)] (with added sulfonated triphenylphosphine) and [Rh(bmim)(cod)(pta)]BF4 catalyzed selectively the transformation of allylic alcohols to the corresponding ketones. The highest catalytic activity, TOF = 152 h−1 (TOF = (mol reacted substrate) × (mol catalyst × time)−1) was observed in redox isomerization of hept-1-en-3-ol ([S]/[cat] = 100). The catalysts were reused in the aqueous phase at least three times, with only modest loss of the catalytic activity and selectivity.

Efficient Redox Isomerization of Allylic Alcohols under Mild Conditions Catalyzed by Arene−Ruthenium(II) Complexes

2006 ◽  
Vol 25 (20) ◽  
pp. 4846-4849 ◽  
Author(s):  
Pascale Crochet ◽  
Mariano A. Fernández-Zúmel ◽  
José Gimeno ◽  
Marcus Scheele
Keyword(s):  
Allylic Alcohols ◽  
Mild Conditions ◽  
Redox Isomerization

Ruthenium Complexes with Dendritic Ferrocenyl Phosphanes: Synthesis, Characterization, and Application in the Catalytic Redox Isomerization of Allylic Alcohols

2015 ◽  
Vol 21 (17) ◽  
pp. 6590-6604 ◽  
Author(s):  
Paul Neumann ◽  
Hanna Dib ◽  
Alix Sournia-Saquet ◽  
Toni Grell ◽  
Marcel Handke ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Allylic Alcohols ◽  
Redox Isomerization

Redox Isomerization of Allylic Alcohols and Amides Using Grubbs’ Catalyst

2003 ◽  
Vol 33 (2) ◽  
pp. 223-228 ◽  
Author(s):  
E. S. Greenwood ◽  
P. J. Parsons ◽  
M. J. Young
Keyword(s):  
Allylic Alcohols ◽  
Grubbs Catalyst ◽  
Redox Isomerization
Sign in / Sign up

Export Citation Format

Share Document