Photoinduced DNA and Protein Cleavage Activity of Ferrocene-Appendedl-Methionine Reduced Schiff Base Copper(II) Complexes of Phenanthroline Bases

2009 ◽  
Vol 28 (7) ◽  
pp. 1992-1994 ◽  
Author(s):  
Tridib K. Goswami ◽  
Mithun Roy ◽  
Munirathinam Nethaji ◽  
Akhil R. Chakravarty

2010 ◽  
Vol 39 (30) ◽  
pp. 7104 ◽  
Author(s):  
Pijus K. Sasmal ◽  
Ritankar Majumdar ◽  
Rajan R. Dighe ◽  
Akhil R. Chakravarty


2010 ◽  
Vol 363 (12) ◽  
pp. 2743-2751 ◽  
Author(s):  
Puja Prasad ◽  
Pijus K. Sasmal ◽  
Ritankar Majumdar ◽  
Rajan R. Dighe ◽  
Akhil R. Chakravarty


CrystEngComm ◽  
2021 ◽  
Author(s):  
Mainak Karmakar ◽  
Antonio Frontera ◽  
Shouvik Chattopadhyay

The formation of an infinite 1D assembly is governed by the H-bonding interactions in the solid state structure of the two zinc complexes. It has been analyzed energetically using DFT calculations and several computational tools.





2018 ◽  
Vol 4 (4) ◽  
pp. 51 ◽  
Author(s):  
Monotosh Mondal ◽  
Maharudra Chakraborty ◽  
Michael G. B. Drew ◽  
Ashutosh Ghosh

Three trinuclear Ni(II)-Na(I) complexes,[Ni2(L1)2NaCl3(H2O)]·H2O (1), [Ni2(L2)2NaCl3(H2O)] (2), and [Ni2(L3)2NaCl3(OC4H10)] (3) have been synthesized using three different NNO donor tridentate reduced Schiff base ligands, HL1= 2-[(3-methylamino-propylamino)-methyl]-phenol, HL2= 2-[(3-methylamino-propylamino)-methyl]-4-chloro-phenol, and HL3= 2-[(3-methylamino-propylamino)-methyl]-6-methoxy-phenol that had been structurally characterized. Among these complexes, 1 and 2 are isostructural in which dinuclearNi(II) units act as metalloligands to bind Na(I) ions via phenoxido and chlorido bridges. The Na(I) atom is five-coordinated, and the Ni(II) atom possesses hexacordinated distorted octahedral geometry. In contrast, in complex 3, two -OMe groups from the dinuclear Ni(II) unit also coordinate to Na(I) to make its geometry heptacordinated pentagonal bipyramidal. The magnetic measurements of complexes 1–3 indicate ferromagnetic interactions between dimeric Ni(II) units with J = 3.97 cm−1, 4.66 cm−1, and 5.50 cm−1for 1–3, respectively, as is expected from their low phenoxido bridging angles (89.32°, 89.39°, and 87.32° for 1–3, respectively). The J values have been calculated by broken symmetry DFT method and found to be in good agreement with the experimental values.





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