Ternary Deep Eutectic Solvents Tasked for Carbon Dioxide Capture

2014 ◽  
Vol 2 (9) ◽  
pp. 2117-2123 ◽  
Author(s):  
Leonhard L. Sze ◽  
Shubha Pandey ◽  
Sudhir Ravula ◽  
Siddharth Pandey ◽  
Hua Zhao ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Deep Eutectic Solvents

Carbon Dioxide Capture with Ionic Liquids and Deep Eutectic Solvents: A New Generation of Sorbents

ChemSusChem ◽  
2016 ◽  
Vol 10 (2) ◽  
pp. 324-352 ◽  
Author(s):  
Shokat Sarmad ◽  
Jyri-Pekka Mikkola ◽  
Xiaoyan Ji
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Carbon Dioxide Capture ◽  
Deep Eutectic Solvents ◽  
New Generation

scholarly journals Intermolecular interactions upon carbon dioxide capture in deep-eutectic solvents

2018 ◽  
Vol 20 (38) ◽  
pp. 24591-24601 ◽  
Author(s):  
Shashi Kant Shukla ◽  
Jyri-Pekka Mikkola
Keyword(s):  
Carbon Dioxide ◽  
Hydrogen Bond ◽  
Intermolecular Interactions ◽  
Carbon Dioxide Capture ◽  
Deep Eutectic Solvents ◽  
Hydrogen Bond Donor ◽  
Hydrogen Bond Acceptor ◽  
Hydrogen Bond Acceptor Basicity

An increase in hydrogen bond acceptor basicity (β) and a decrease in hydrogen bond donor acidity (α) simultaneously promotes higher CO2 uptake in deep eutectic solvents.

scholarly journals Is basicity the sole criterion for attaining high carbon dioxide capture in deep-eutectic solvents?

2020 ◽  
Vol 22 (3) ◽  
pp. 966-970
Author(s):  
Shashi Kant Shukla ◽  
Dariush Nikjoo ◽  
Jyri-Pekka Mikkola
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Deep Eutectic Solvents ◽  
Synergistic Interaction ◽  
High Carbon ◽  
Donor And Acceptor ◽  
Sole Criterion ◽  
High Carbon Dioxide

Compared to the large |α–β| in DESs, a relatively small |α–β| brings “synergistic interaction“ into play and allows the donor and acceptor components to react efficiently with CO2 molecules in DES.

scholarly journals Unusual temperature-promoted carbon dioxide capture in deep-eutectic solvents: the synergistic interactions

2019 ◽  
Vol 55 (27) ◽  
pp. 3939-3942 ◽  
Author(s):  
Shashi Kant Shukla ◽  
Jyri-Pekka Mikkola
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Deep Eutectic Solvents ◽  
Synergistic Interaction ◽  
Synergistic Interactions ◽  
Donor And Acceptor

Equivalent donor and acceptor tendencies in DESs bring strong synergistic interaction into play and result in high CO2 uptake by lowering the ΔH° and ΔS°.

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