scholarly journals Unusual temperature-promoted carbon dioxide capture in deep-eutectic solvents: the synergistic interactions

2019 ◽  
Vol 55 (27) ◽  
pp. 3939-3942 ◽  
Author(s):  
Shashi Kant Shukla ◽  
Jyri-Pekka Mikkola
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Deep Eutectic Solvents ◽  
Synergistic Interaction ◽  
Synergistic Interactions ◽  
Donor And Acceptor

Equivalent donor and acceptor tendencies in DESs bring strong synergistic interaction into play and result in high CO2 uptake by lowering the ΔH° and ΔS°.

scholarly journals Is basicity the sole criterion for attaining high carbon dioxide capture in deep-eutectic solvents?

2020 ◽  
Vol 22 (3) ◽  
pp. 966-970
Author(s):  
Shashi Kant Shukla ◽  
Dariush Nikjoo ◽  
Jyri-Pekka Mikkola
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Deep Eutectic Solvents ◽  
Synergistic Interaction ◽  
High Carbon ◽  
Donor And Acceptor ◽  
Sole Criterion ◽  
High Carbon Dioxide

Compared to the large |α–β| in DESs, a relatively small |α–β| brings “synergistic interaction“ into play and allows the donor and acceptor components to react efficiently with CO2 molecules in DES.

Ternary Deep Eutectic Solvents Tasked for Carbon Dioxide Capture

2014 ◽  
Vol 2 (9) ◽  
pp. 2117-2123 ◽  
Author(s):  
Leonhard L. Sze ◽  
Shubha Pandey ◽  
Sudhir Ravula ◽  
Siddharth Pandey ◽  
Hua Zhao ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Deep Eutectic Solvents

Carbon Dioxide Capture with Ionic Liquids and Deep Eutectic Solvents: A New Generation of Sorbents

ChemSusChem ◽  
2016 ◽  
Vol 10 (2) ◽  
pp. 324-352 ◽  
Author(s):  
Shokat Sarmad ◽  
Jyri-Pekka Mikkola ◽  
Xiaoyan Ji
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Carbon Dioxide Capture ◽  
Deep Eutectic Solvents ◽  
New Generation

scholarly journals Intermolecular interactions upon carbon dioxide capture in deep-eutectic solvents

2018 ◽  
Vol 20 (38) ◽  
pp. 24591-24601 ◽  
Author(s):  
Shashi Kant Shukla ◽  
Jyri-Pekka Mikkola
Keyword(s):  
Carbon Dioxide ◽  
Hydrogen Bond ◽  
Intermolecular Interactions ◽  
Carbon Dioxide Capture ◽  
Deep Eutectic Solvents ◽  
Hydrogen Bond Donor ◽  
Hydrogen Bond Acceptor ◽  
Hydrogen Bond Acceptor Basicity

An increase in hydrogen bond acceptor basicity (β) and a decrease in hydrogen bond donor acidity (α) simultaneously promotes higher CO2 uptake in deep eutectic solvents.

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