A very large number of observations have been made of the refractive indices and densities of aqueous solutions of inorganic salts and acids: in England, more especially, by Dr. J. H. Gladstone, who in a paper in the ‘Philosophical Transactions’ for 1870, gave the values he had obtained for the refractive indices and densities of some 160 salts and acids; and in a series of papers published subsequently in the 'Journal of the Chemical Society,’ has given the results of further observations. Most, however, of these determinations have been made with solutions of different strengths, and at different temperatures, and, therefore, I venture to bring before the Royal Society an account of some observations I have made of the refractive indices and densities of normal and semi-normal aqueous solutions of hydrogen chloride, and the chlorides of the alkalis at a uniform temperature of 18°.