Kinetics of desolvation from crystalline inclusion compounds of a diol host with methanol and ethanol

1997 ◽  
pp. 585-588 ◽  
Author(s):  
Susan A. Bourne ◽  
Bruce M. Oom ◽  
Fumio Toda
Keyword(s):  
Inclusion Compounds ◽  
Crystalline Inclusion ◽  
Crystalline Inclusion Compounds ◽  
Kinetics Of

scholarly journals Crystalline Inclusion Compounds of a Palladacyclic Tetraol Host Featuringo-Carborane Units

2017 ◽  
Vol 2017 (38-39) ◽  
pp. 4589-4598 ◽  
Author(s):  
Min Ying Tsang ◽  
Clara Viñas ◽  
Francesc Teixidor ◽  
Duane Choquesillo-Lazarte ◽  
José Giner Planas
Keyword(s):  
Inclusion Compounds ◽  
Crystalline Inclusion ◽  
Crystalline Inclusion Compounds

Formation of crystalline inclusion compounds of poly (vinyl chloride) of different stereoregularity with γ-cyclodextrin

2007 ◽  
Vol 45 (12) ◽  
pp. 2503-2513 ◽  
Author(s):  
Gerardo Martínez ◽  
Marián A. Gómez ◽  
Silvia Villar-Rodil ◽  
Leoncio Garrido ◽  
Alan E. Tonelli ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Inclusion Compounds ◽  
Crystalline Inclusion ◽  
Crystalline Inclusion Compounds ◽  
Poly Vinyl Chloride

TRIMETHYL ORTHOBORATE – AMINE INCLUSION COMPOUNDS

1962 ◽  
Vol 40 (9) ◽  
pp. 1805-1815
Author(s):  
D. M. Young ◽  
C. D. Anderson
Keyword(s):  
Vapor Pressure ◽  
Inclusion Compounds ◽  
Room Temperature ◽  
Secondary Amines ◽  
Crystalline Inclusion ◽  
X Ray Diffraction ◽  
Crystalline Inclusion Compounds ◽  
X Ray ◽  
New Class ◽  
Primary And Secondary Amines

A new class of non-stoichiometric crystalline inclusion compounds has been discovered, having the general formula[Formula: see text]where 0.5 < n < 1.0 and 0 < x < 3 depending on the method of preparation and on the nature of the amine and solvent. Such compounds have been prepared with ammonia and a variety of primary and secondary amines. Among the solvents which can be incorporated into the crystals are alcohols, ketones, ethers, esters, nitriles, nitroparaffins, and hydrocarbons. Such compounds are also formed by triphenyl orthoborate, with 1.7 < n < 2.4 and 1.2 < x < 1.6.The incorporated solvent has been shown to exert a definite vapor pressure. Furthermore, many of the compounds sublime at room temperature to form large transparent crystals which also contain incorporated solvent. The mechanism probably involves dissociation, followed by reassociation on the walls of the vessel. Preliminary X-ray diffraction measurements suggest that the trimethyl orthoborate – ammonia inclusion compounds have essentially the same crystal lattice as pure trimethyl orthoborate – ammonia.

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