Analysis and characterization of water treatment plant sludges by X-ray fluorescence spectrometry

The Analyst ◽  
1995 ◽  
Vol 120 (5) ◽  
pp. 1267 ◽  
Author(s):  
H. Margaret West ◽  
Jess Cawley ◽  
Robert Wills
2019 ◽  
Vol 80 (11) ◽  
pp. 2117-2130
Author(s):  
Ivan Matías Ragessi ◽  
Carlos Marcelo García ◽  
Santiago Márquez Damián ◽  
Cecilia Pozzi Piacenza ◽  
Mariano Ignacio Cantero

Abstract This paper presents a detailed characterization of turbulence in the incoming flow to the clarification component of a water treatment plant, ‘Los Molinos’ (Córdoba, Argentina). The main problems were related to the presence of turbulent flow patterns throughout the treatment, affecting the proper development of the physical processes required for water clarification. Namely: (a) a poor hydraulic design that could produce a non-homogeneous spatial distribution of the flow, recirculation zones and flow stagnation, and a non-uniform discharge distribution among the sedimentation units as a result of different cross-sectional dimensions of the transverse-channel, and (b) high turbulence intensity that affect the flocs' size as well as the efficiency of the settling tanks and filters. Firstly, a detailed in-situ experimental characterization of the turbulent flow was undertaken. An acoustic Doppler velocimeter (ADV) was used to characterize the flow turbulence, whereas for discharge measurements and mean flow velocity field an acoustic Doppler current profiler (ADCP) was employed. Secondly, a numerical model, based on the Reynolds-averaged Navier–Stokes (RANS) equations and the - turbulence closure model, was validated with the experimental data. Finally, based on the results, a diagnosis and recommendations were made for the optimization of the hydraulic design of the water treatment plant.


2015 ◽  
Vol 77 (32) ◽  
Author(s):  
Mohd Asri Md Nor ◽  
Alia Syafiqah Abdul Hamed ◽  
Faisal Hj Ali ◽  
Ong Keat Khim

Every year, large quantity of water treatment sludge (WTS) is produced from water treatment plant in Malaysia. Sanitary landfill disposal of sludge at authorized sites is the common practice in Malaysia. However, searching the suitable site for landfill is the major problem as the amount of sludge produced keeps on increasing. Reuse of the sludge could be an alternative to disposal. This study investigated the reusability of WTS as brick making material. The performance of clay-WTS bricks produced by mixing clay with different percentages of WTS with increments of 20% from 0% up to 100% was investigated. Each molded brick with optimum moisture content was pressed under constant pressure, oven-dried at 100˚C for 24 hours followed by heating at 600˚C for 2 hours and 1000˚C for 3 hours. Scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive X-ray (EDX) analysis were used to characterize clay, WTS and clay-WTS bricks.  The performance of the bricks were evaluated with firing shrinkage, loss on ignition (LOI), water absorption, bulk density, and compressive strength tests. Increasing the sludge content results in a decrease of brick firing shrinkage, and increase of water absorption and compressive strength. The results revealed that the brick with 100% by weight of sludge could generate the highest compressive strength of 17.123N/mm2. It can be concluded that the bricks with 20 to 100% of water treatment sludge comply with the Malaysian Standard MS7.6:1972, which can fulfill the general requirement for usage of clay bricks in wall construction.


2016 ◽  
Vol 701 ◽  
pp. 138-142 ◽  
Author(s):  
Mohamat Yusuff Soleha ◽  
Keat Khim Ong ◽  
Wan Yunus Wan Md Zin ◽  
Ahmad Mansor ◽  
Fitrianto Anwar ◽  
...  

Use of alum as a coagulant in drinking water treatment process generates an alum sludge as a waste product. Since the amount of this sludge is huge, it is crucial for a water work management to properly handle and dispose of this sludge. Reuse of this alum sludge as a solid adsorbent is one of the proposed applications for this material but modification and characterization are needed to alter and identify its properties so that optimum benefits are obtained. This paper reports characterization of raw and thermally treated alum sludge. The raw alum sludge was collected from a local water treatment plant and heated at 300 °C and 800 °C for 7 hours using a furnace before characterization using scanning electron microscopy energy (SEM), thermogravimetric (TGA), X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET). The results showed that surface morphology, thermal properties, microstructure, surface area and porosity of the sludge were affected by heating temperature whereby increase the heating temperature resulted in improved thermal stability of the sludge. The results also revealed that both raw and thermally treated alum sludge were mesoporous materials and mainly compose of quartz and kaolinite. It can be said that the sludge could be a good candidate as low cost adsorbent.


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