Influence of pH, surfactant and synergic agent on the luminescent properties of terbium chelated with benzoic acid derivatives in aqueous solutions

The Analyst ◽  
2000 ◽  
Vol 125 (8) ◽  
pp. 1487-1490 ◽  
Author(s):  
Nadine Arnaud ◽  
Joseph Georges

2006 ◽  
Vol 29 (18) ◽  
pp. 2663-2675 ◽  
Author(s):  
Bogusław Buszewski ◽  
Sylwia Kowalska ◽  
Gabriela Karasová ◽  
Jozef Lehotay




2016 ◽  
Vol 1 (6) ◽  
pp. 1123-1131 ◽  
Author(s):  
Samuele Staderini ◽  
Giulia Tuci ◽  
Mila D'Angelantonio ◽  
Francesco Manoli ◽  
Ilse Manet ◽  
...  


2019 ◽  
Author(s):  
K Georgousaki ◽  
N Tsafantakis ◽  
S Gumeni ◽  
V González-Menéndez ◽  
G Lambrinidis ◽  
...  


2019 ◽  
Vol 15 (2) ◽  
pp. 186-195 ◽  
Author(s):  
Samridhi Thakral ◽  
Vikramjeet Singh

Background: Postprandial hyperglycemia can be reduced by inhibiting major carbohydrate hydrolyzing enzymes, such as α-glucosidase and α-amylase which is an effective approach in both preventing and treating diabetes. Objective: The aim of this study was to synthesize a series of 2,4-dichloro-5-[(N-aryl/alkyl)sulfamoyl] benzoic acid derivatives and evaluate α-glucosidase and α-amylase inhibitory activity along with molecular docking and in silico ADMET property analysis. Method: Chlorosulfonation of 2,4-dichloro benzoic acid followed by reaction with corresponding anilines/amines yielded 2,4-dichloro-5-[(N-aryl/alkyl)sulfamoyl]benzoic acid derivatives. For evaluating their antidiabetic potential α-glucosidase and α-amylase inhibitory assays were carried out. In silico molecular docking studies of these compounds were performed with respect to these enzymes and a computational study was also carried out to predict the drug-likeness and ADMET properties of the title compounds. Results: Compound 3c (2,4-dichloro-5-[(2-nitrophenyl)sulfamoyl]benzoic acid) was found to be highly active having 3 fold inhibitory potential against α-amylase and 5 times inhibitory activity against α-glucosidase in comparison to standard drug acarbose. Conclusion: Most of the synthesized compounds were highly potent or equipotent to standard drug acarbose for inhibitory potential against α-glucosidase and α-amylase enzyme and hence this may indicate their antidiabetic activity. The docking study revealed that these compounds interact with active site of enzyme through hydrogen bonding and different pi interactions.



2010 ◽  
Vol 9 (4) ◽  
pp. 198-204 ◽  
Author(s):  
Sadagopan Magesh ◽  
Nongluk Sriwilaijaroen ◽  
Vats Savita ◽  
Hiromune Ando ◽  
Taeko Miyagi ◽  
...  


1981 ◽  
Vol 46 (7) ◽  
pp. 1566-1576
Author(s):  
František Vašák ◽  
Václav Kolář ◽  
Zdeněk Brož

Theoretical relation derived in the last study for calculation of the mass transfer coefficient in the region of not fully developed concentration profile at high Schmidt numbers has been verified experimentally. This experimental study has been devoted to measurements of the rate of benzoic acid dissolution into aqueous solutions of glycerol from the internal surface of the pipe of circular cross section in the range 933 ⪬ Sc ⪬ 225 000 and 5 000 ⪬ Re ⪬ 50 000. It has been possible to explain on basis of the theoretical model, the differences between the data of various authors and to obtain a unified description of the phenomena.



Author(s):  
Ganesh Prasad Mishra ◽  
Rajesh Sharma ◽  
Mukul Jain ◽  
Debdutta Bandyopadhyay


2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Miao Guo ◽  
Xiangtao Kong ◽  
Chunzhi Li ◽  
Qihua Yang

AbstractHydrogenation of benzoic acid (BA) to cyclohexanecarboxylic acid (CCA) has important industrial and academic significance, however, the electron deficient aromatic ring and catalyst poisoning by carboxyl groups make BA hydrogenation a challenging transformation. Herein, we report that Pt/TiO2 is very effective for BA hydrogenation with, to our knowledge, a record TOF of 4490 h−1 at 80 °C and 50 bar H2, one order higher than previously reported results. Pt/TiO2 catalysts with electron-deficient and electron-enriched Pt sites are obtained by modifying the electron transfer direction between Pt and TiO2. Electron-deficient Pt sites interact with BA more strongly than electron-rich Pt sites, helping the dissociated H of the carboxyl group to participate in BA hydrogenation, thus enhancing its activity. The wide substrate scope, including bi- and tri-benzoic acids, further demonstrates the high efficiency of Pt/TiO2 for hydrogenation of BA derivatives.



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