Determination of alkaloids in capsules, milk and ethanolic extracts of poppy (Papaver somniferum L.) by ATR-FT-IR and FT-Raman spectroscopy

The Analyst ◽  
2004 ◽  
Vol 129 (10) ◽  
pp. 917-920 ◽  
Author(s):  
Hartwig Schulz ◽  
Malgorzata Baranska ◽  
Rolf Quilitzsch ◽  
Wolfgang Schütze
1996 ◽  
Vol 74 (9) ◽  
pp. 1671-1681 ◽  
Author(s):  
Jack Passmore ◽  
Paul D. Boyle ◽  
Gabriele Schatte ◽  
Todd Way ◽  
T. Stanley Cameron

Alternative and, in some cases, improved syntheses of the salts MX3(As/Sb)F6 (M = S, Se) and SCl3(SbCl6/AlCl4) are described. In addition, the synthesis of SeCl3SbF6 is reported. The compounds were characterized by FT–Raman spectroscopy and the X-ray crystal structures of SeCl3AsF6 (also 77Se NMR) and a new phase of SBr3SbF6 were determined. Crystals of SeCl3AsF6 and SBr3SbF6 are monoclinic, space group P21/c with [values for SBr3SbF6 in brackets] a = 7.678(1) [8.137(1)] Å, b = 9.380(3) [9.583(2)] Å, c = 11.920(3) [12.447(2)] Å, β = 98.19(2)° [97.36(1)]°, V = 849.72(3) [962.6(3)] Å3,z = 4, Dx = 2.925 [3.502] Mg m−3, R = 0.0525 [0.055], and Rw = 0.0554 [0.060] for 1151 [1472] observed reflections. Key words: MX3+ salts, FT–Raman spectroscopy, X-ray crystal structures of SeCl3AsF6, SBr3SbF6, and preparation of SeCl3SbF6.


LWT ◽  
2020 ◽  
Vol 121 ◽  
pp. 108959 ◽  
Author(s):  
Agnieszka Nawrocka ◽  
Magdalena Krekora ◽  
Zbigniew Niewiadomski ◽  
Monika Szymańska-Chargot ◽  
Ada Krawęcka ◽  
...  

2005 ◽  
Vol 39 (1-2) ◽  
pp. 275-280 ◽  
Author(s):  
B. De Spiegeleer ◽  
D. Seghers ◽  
R. Wieme ◽  
J. Schaubroeck ◽  
F. Verpoort ◽  
...  

1993 ◽  
Vol 9 (5) ◽  
pp. 317-324 ◽  
Author(s):  
W SHIN ◽  
X LI ◽  
B SCHWARTZ ◽  
S WUNDER ◽  
G BARAN

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