Synthesis, solid-state molecular structure and solution dynamics of new alkoxy stannylene-transition metal complexes

2005 ◽  
Vol 29 (1) ◽  
pp. 154 ◽  
Author(s):  
Michael Veith ◽  
Markus Ehses ◽  
Volker Huch
Keyword(s):  
Molecular Structure ◽  
Solid State ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Solution Dynamics

Transition Metal Complexes of Diazenes, XVII [1]. Reactions of 1,2-Diazetines and 1,2-Diazetine-N-oxides with Iron Carbonyls

1982 ◽  
Vol 37 (4) ◽  
pp. 463-467 ◽  
Author(s):  
A. Albini ◽  
H. Kisch ◽  
C. Krüger ◽  
An-Pei Chiang
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes ◽  
Lone Pair ◽  
X Ray ◽  
Iron Carbonyls

Enneacarbonyldiiron reacts with 3,3,4,4-tetramethyl-1,2-diazetine (L) or its mono-N-oxide (L′) to form complexes (L)Fe(CO)4 (3), (L)Fe2(CO)7 (4), (L)Fe2(CO)6 (5), or (L′)Fe(CO)4 (6), and small amounts of deoxygenated 4 and 5, respectively. Formation and stability of the complexes is compared with those of ligands with smaller and larger ring sizes and discussed in terms of the electronic properties of the ligand lone-pair Orbitals. The molecular structure of 4 is established by X-ray analysis.

2,2′-Bipyrimidine transition metal complexes: Synthesis, reaction chemistry and solid state structures

2008 ◽  
Vol 693 (23) ◽  
pp. 3479-3489 ◽  
Author(s):  
Alexander Jakob ◽  
Petra Ecorchard ◽  
Katrin Köhler ◽  
Heinrich Lang
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Synthesis Reaction ◽  
Solid State Structures
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