The P2-Na2/3Co2/3Mn1/3O2 phase: structure, physical properties and electrochemical behavior as positive electrode in sodium battery

2011 ◽  
Vol 40 (36) ◽  
pp. 9306 ◽  
Author(s):  
D. Carlier ◽  
J. H. Cheng ◽  
R. Berthelot ◽  
M. Guignard ◽  
M. Yoncheva ◽  
...  
2020 ◽  
Vol 129 (1D) ◽  
pp. 5-13
Author(s):  
Nguyen TruongTho

The effect of the ZnO addition in pure perovskite PZT-PMnN-PSbN ceramics sintered from 950 to 1200oC has been investigated. The phase structure of ceramics changes from rhombohedral to tetragonal and the temperature decreases with the increase of the ZnO content. The limitation of Zn2+ concentration for the solubility in PZT–PMnN–PSbN systems is about 0.25% wt., at which the ceramic shows some good physical properties such as the density of 8.20 g/cm3, some dielectric constants including εr = 1,555 and εmax = 32,900. The highest value of εmax about 22,000 was found at 1 kHz at the temperature of Tm around 575 K. Using an extended Curie-Weiss law the diffuse phase transition was determined. Cole-Cole analyses showed the non-Debye type relaxation in the system


2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Nguyen Dinh Tung Luan ◽  
Le Dai Vuong ◽  
Truong Van Chuong ◽  
Nguyen Truong Tho

The 0.9Pb(ZrxTi1−x)O3-0.07Pb(Mn1/3Nb2/3)O3-0.03Pb(Sb1/2Nb1/2)O3(PZT-PMnN-PSN) ceramics were prepared by columbite method. The phase structure of the ceramic samples was analyzed. Results show that the pure perovskite phase is in all ceramics specimens. The effect of the Zr/Ti ratio on the region of morphotropic phase boundary for PZT-PMnN-PSN ceramics was studied. Experimental results show that the phase structure of ceramics changes from tetragonal to rhombohedral with the increase of the content of Zr/Ti ratio in the system. The composition of PZT-PMnN-PSN ceramics near the morphotropic phase boundary obtained is the ratio of Zr/Ti: 49/51. At this ratio, the ceramic has the optimal electromechanical properties: thekp=0.61, theεmax=29520, thed31=-236 pC/N, theQm=2400, high remanent polarization (Pr=49.2 μC·cm−2), and low coercive fieldEc=10.28 kV·cm−1.


2012 ◽  
Vol 70 (5) ◽  
pp. 1575-1590 ◽  
Author(s):  
Anna Szymczyk ◽  
Sandra Paszkiewicz ◽  
Zbigniew Roslaniec

2020 ◽  
Vol 878 ◽  
pp. 114539
Author(s):  
Dorcas Zide ◽  
Cecil Felix ◽  
Tobie Oosthuysen ◽  
Bernard Jan Bladergroen

2021 ◽  
Vol 130 (1B) ◽  
pp. 13-20
Author(s):  
Nguyen TruongTho ◽  
Le Ngoc Minh ◽  
Le Tran Uyen Tu ◽  
Dung THi Hoai Trang ◽  
Le Phuoc Dinh ◽  
...  

In this study, Bi0.5(Na1–xKx)0.5SnO3 (BNKS) ceramics (x = 0, 0.1, 0.2, 0.3, and 0.4) were fabricated via ultrasound wave before milling. The time of ball milling decreased from 20 to 1 h. The X-ray diffraction patterns show that the BNKS has a single-phase structure. When the potassium content increases, the phase structure of the ceramics changes from rhombohedral to tetragonal. When sintered at 1100 °C and x = 0.2, the ceramics’ physical properties are the best with the mass density of 5.59 g/cm3, the electromechanical coupling constants kp of 0,31 and kt of 0.27, the remanent polarization of      11.9 µC/cm; the dielectric constant εr of 1131, and the highest dielectric constant emax of 4800.


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