Syngas production by simultaneous splitting of H2O and CO2via ceria redox reactions in a high-temperature solar reactor

2012 ◽  
Vol 5 (3) ◽  
pp. 6098-6103 ◽  
Author(s):  
Philipp Furler ◽  
Jonathan R. Scheffe ◽  
Aldo Steinfeld
2016 ◽  
Vol 41 (44) ◽  
pp. 19936-19946 ◽  
Author(s):  
Guene L. Bachirou ◽  
Yong Shuai ◽  
Jiahui Zhang ◽  
Xing Huang ◽  
Yuan Yuan ◽  
...  

RSC Advances ◽  
2020 ◽  
Vol 10 (60) ◽  
pp. 36617-36626
Author(s):  
Manabu Heya ◽  
Xiang Gao ◽  
Antonio Tricoli ◽  
Wojciech Lipiński

Specific surface area is a key parameter determining the rates of thermochemical redox reactions in metal oxides.


RSC Advances ◽  
2021 ◽  
Vol 11 (37) ◽  
pp. 23095-23104
Author(s):  
Asim Riaz ◽  
Wojciech Lipiński ◽  
Adrian Lowe

Cerium doping into the V2O5 lattice forms a reversible V2O3/VO redox pair after sequential methane partial oxidation and CO2/H2O splitting reactions and produces syngas (H2, CO) with fast rates and high oxygen exchange capacity.


2015 ◽  
Vol 69 ◽  
pp. 1810-1818 ◽  
Author(s):  
P. Parthasarathy ◽  
P. Le Clercq

Author(s):  
Nicolas Piatkowski ◽  
Christian Wieckert ◽  
Aldo Steinfeld

Gasification of coal, biomass, and other carbonaceous materials for high-quality syngas production is considered using concentrated solar energy as the source of high-temperature process heat. The solar reactor consists of two cavities separated by a SiC-coated graphite plate, with the upper one serving as the radiative absorber and the lower one containing the reacting packed bed that shrinks as the reaction progresses. A 5-kW prototype reactor with an 8 cm-depth, 14.3 cm-diameter cylindrical bed was fabricated and tested in the High-Flux Solar Simulator at PSI, subjected to solar flux concentrations up to 2300 suns. Beech charcoal was used as a model feedstock and converted into high-quality syngas (predominantly H2 and CO) with packed-bed temperatures up to 1500 K, an upgrade factor of the calorific value of 1.33, and an energy conversion efficiency of 29%. Pyrolysis was evident through the evolution of higher gaseous hydrocarbons during heating of the packed bed. The engineering design, fabrication, and testing of the solar reactor are described.


2010 ◽  
Vol 3 (10) ◽  
pp. 1382 ◽  
Author(s):  
Qingxi Fu ◽  
Corentin Mabilat ◽  
Mohsine Zahid ◽  
Annabelle Brisse ◽  
Ludmila Gautier

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