scholarly journals The influence of counter ion and ligandmethyl substitution on the solid-state structures and photophysical properties of mercury(ii) complexes with (E)-N-(pyridin-2-ylmethylidene)arylamines

2013 ◽  
Vol 42 (5) ◽  
pp. 1905-1920 ◽  
Author(s):  
Tushar S. Basu Baul ◽  
Sajal Kundu ◽  
Sivaprasad Mitra ◽  
Herbert Höpfl ◽  
Edward R. T. Tiekink ◽  
...  
Keyword(s):  
Solid State ◽  
Photophysical Properties ◽  
Counter Ion ◽  
Solid State Structures

Revisiting Borylanilines: Unique Solid-State Structures and Insight into Photophysical Properties

2013 ◽  
Vol 32 (10) ◽  
pp. 3129-3133 ◽  
Author(s):  
Pagidi Sudhakar ◽  
Sanjoy Mukherjee ◽  
Pakkirisamy Thilagar
Keyword(s):  
Solid State ◽  
Photophysical Properties ◽  
Solid State Structures ◽  
Insight Into

Dicyanovinyl Heterotetracenes: Synthesis, Solid-State Structures, and Photophysical Properties

2009 ◽  
Vol 74 (19) ◽  
pp. 7322-7327 ◽  
Author(s):  
Chunyan Du ◽  
Jianming Chen ◽  
Yunlong Guo ◽  
Kun Lu ◽  
Shanghui Ye ◽  
...  
Keyword(s):  
Solid State ◽  
Photophysical Properties ◽  
Solid State Structures

Effects of counter-ion size on solid state structures of M2+(Nitrilotriacetate) complexes

2005 ◽  
Vol 358 (4) ◽  
pp. 1284-1288 ◽  
Author(s):  
Nathan R. Lien ◽  
Mitchell A. Timmons ◽  
Gloria J.H. Belkin ◽  
James R. Holst ◽  
Merryn L. Janzen ◽  
...  
Keyword(s):  
Solid State ◽  
Counter Ion ◽  
Ion Size ◽  
Solid State Structures

Lanthanide(III) Complexes of Bis-semicarbazone and Bis-imine-Substituted Phenanthroline Ligands: Solid-State Structures, Photophysical Properties, and Anion Sensing

2012 ◽  
Vol 18 (52) ◽  
pp. 16784-16792 ◽  
Author(s):  
Sandeep Nadella ◽  
Paulraj M. Selvakumar ◽  
Eringathodi Suresh ◽  
Palani S. Subramanian ◽  
Markus Albrecht ◽  
...  
Keyword(s):  
Solid State ◽  
Photophysical Properties ◽  
Anion Sensing ◽  
Solid State Structures ◽  
Phenanthroline Ligands

Solid state structures and photophysical properties of (trimethylsilyl)methyl-substituted anthracenes and pyrenes

2008 ◽  
pp. 2134 ◽  
Author(s):  
Masaki Shimizu ◽  
Hironori Tatsumi ◽  
Kenji Mochida ◽  
Tamejiro Hiyama
Keyword(s):  
Solid State ◽  
Photophysical Properties ◽  
Solid State Structures

Luminescent sensing profiles based on anion-responsive lanthanide(iii) quinolinecarboxylate materials: solid-state structures, photophysical properties, and anionic species recognition

2015 ◽  
Vol 3 (9) ◽  
pp. 2003-2015 ◽  
Author(s):  
Wentao Xu ◽  
Youfu Zhou ◽  
Decai Huang ◽  
Mingyi Su ◽  
Kun Wang ◽  
...  
Keyword(s):  
Solid State ◽  
Photophysical Properties ◽  
Species Recognition ◽  
Detection Limits ◽  
Anionic Species ◽  
Solid State Structures ◽  
Luminescent Sensing

Eu2PQC6 has been developed to detect HSO4− and H2PO4− through different recognition mechanisms with low detection limits.

scholarly journals Fluorinated azobenzenes as supramolecular halogen-bonding building blocks

2019 ◽  
Vol 15 ◽  
pp. 2013-2019 ◽  
Author(s):  
Esther Nieland ◽  
Oliver Weingart ◽  
Bernd M Schmidt
Keyword(s):  
Solid State ◽  
Dft Calculations ◽  
Visible Light ◽  
Half Life ◽  
Photophysical Properties ◽  
Bathochromic Shift ◽  
Halogen Bonding ◽  
Building Blocks ◽  
Partial Overlap

ortho-Fluoroazobenzenes are a remarkable example of bistable photoswitches, addressable by visible light. Symmetrical, highly fluorinated azobenzenes bearing an iodine substituent in para-position were shown to be suitable supramolecular building blocks both in solution and in the solid state in combination with neutral halogen bonding acceptors, such as lutidines. Therefore, we investigate the photochemistry of a series of azobenzene photoswitches. Upon introduction of iodoethynyl groups, the halogen bonding donor properties are significantly strengthened in solution. However, the bathochromic shift of the π→π* band leads to a partial overlap with the n→π* band, making it slightly more difficult to address. The introduction of iodine substituents is furthermore accompanied with a diminishing thermal half-life. A series of three azobenzenes with different halogen bonding donor properties are discussed in relation to their changing photophysical properties, rationalized by DFT calculations.

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